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- W2001176716 abstract "The relation between the electrical conductivities and the chemistry of graphite-AsF5 compounds has been investigated. Comparisons are made with graphite+-AsF6− relatives and with graphite compounds of the third-series transition metal fluorides. The room-temperature, basal-plane conductivity of C8nAsF5 is found to be approximately independent of stage for n = 1 to 3, with a range of values ± 12% about a mean value of 2.9 × 105 (Ω cm)−1 — approximately half the value for copper. The chemistry of C8nAsF5 for n ⩾ 2 is dominated by the disproportionation of the AsF5 molecule and the oxidation of the graphite according to 2e− + 3AsF5å 2AsF6− + AsF3. For second- and higher-stage materials, AsF3 can be removed and added back again to the graphite compound without significant change in the conductivity. Second- and higher-stage graphite-AsF6 salts, C12nAsF6 (n ⩾ 2), also have conductivities comparable with those of their C8nAsF5 relatives of the same stage. In the first-stage salt, which has a composition range C12AsF6 to C8AsF6, basal-plane conductivities are approximately an order of magnitude lower than in the second- and third-stage salts. Fluorination of C8nAsF5 materials generates AsF6− salts, but such salts usually incorporate extra fluorine to a limiting composition CxAsF6 · 12F2. These fluorine-rich systems have lower basal-plane conductivities than do their CxAsF6 relatives." @default.
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- W2001176716 date "1981-04-01" @default.
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- W2001176716 title "The electrical conductivity of graphite-AsF5 intercalation compounds and their relationship to other graphite-MF6 salts" @default.
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