FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001184349> ?p ?o ?g. }

• W2001184349 endingPage "19567" @default.
• W2001184349 startingPage "19560" @default.
• W2001184349 abstract "Low-temperature adsorption of carbon monoxide on an ordered periodic mesoporous organosilica (1,4-phenylenesilica PMO) was studied by means of infrared spectroscopy and theoretical calculations on cluster models. Basically, three types of adsorbed CO species were found to be simultaneously formed at a low CO coverage: (i) physisorbed species having the CO molecule interacting only with a benzene ring, (ii) hydrogen-bonded species having the CO molecule interacting with a silanol group through the carbon atom, and (iii) hydrogen-bonded species having the CO molecule interacting with a silanol group through the oxygen atom. However, both hydrogen-bonded species showed also a residual (lateral) interaction of the CO molecule with a neighboring benzene ring. This residual interaction accounts for an overall adsorption enthalpy (ΔH0) that is significantly larger than that involving the interaction of CO with silica. Thus, the C-bonded species ii showed ΔH0 = −13.2 kJ mol−1 (as determined by variable-temperature infrared spectroscopy) to be compared with that of ΔH0 = −11 kJ mol−1 previously reported for the interaction between CO and silica silanol groups. Also remarkable is the relatively large value of adsorption enthalpy, ΔH0 = −10.6 kJ mol−1, showed by the physisorbed species involving only interaction between CO and a benzene ring." @default.
• W2001184349 created "2016-06-24" @default.
• W2001184349 creator A5001686080 @default.
• W2001184349 creator A5025656285 @default.
• W2001184349 creator A5032151940 @default.
• W2001184349 creator A5036535606 @default.
• W2001184349 creator A5038824563 @default.
• W2001184349 creator A5046763472 @default.
• W2001184349 creator A5053734699 @default.
• W2001184349 date "2008-11-14" @default.
• W2001184349 modified "2023-10-16" @default.
• W2001184349 title "IR and Computational Characterization of CO Adsorption on a Model Surface, the Phenylene Periodic Mesoporous Organosilca with Crystalline Walls" @default.
• W2001184349 cites W1519313568 @default.
• W2001184349 cites W1520925341 @default.
• W2001184349 cites W1864753689 @default.
• W2001184349 cites W1960530629 @default.
• W2001184349 cites W1967311510 @default.
• W2001184349 cites W1967655020 @default.
• W2001184349 cites W1968293312 @default.
• W2001184349 cites W1975442471 @default.
• W2001184349 cites W1975493559 @default.
• W2001184349 cites W1981699152 @default.
• W2001184349 cites W1982013132 @default.
• W2001184349 cites W1990706955 @default.
• W2001184349 cites W1996460640 @default.
• W2001184349 cites W1997115427 @default.
• W2001184349 cites W2008997084 @default.
• W2001184349 cites W2016460360 @default.
• W2001184349 cites W2027016305 @default.
• W2001184349 cites W2031414552 @default.
• W2001184349 cites W2032442093 @default.
• W2001184349 cites W2036563090 @default.
• W2001184349 cites W2042442357 @default.
• W2001184349 cites W2044591029 @default.
• W2001184349 cites W2053045486 @default.
• W2001184349 cites W2053638179 @default.
• W2001184349 cites W2072750734 @default.
• W2001184349 cites W2075589044 @default.
• W2001184349 cites W2078146328 @default.
• W2001184349 cites W2078220488 @default.
• W2001184349 cites W2083422465 @default.
• W2001184349 cites W2090510107 @default.
• W2001184349 cites W2103637866 @default.
• W2001184349 cites W2158141669 @default.
• W2001184349 cites W2167039908 @default.
• W2001184349 doi "https://doi.org/10.1021/jp805981a" @default.
• W2001184349 hasPublicationYear "2008" @default.
• W2001184349 type Work @default.
• W2001184349 sameAs 2001184349 @default.
• W2001184349 citedByCount "17" @default.
• W2001184349 countsByYear W20011843492012 @default.
• W2001184349 countsByYear W20011843492014 @default.
• W2001184349 countsByYear W20011843492015 @default.
• W2001184349 countsByYear W20011843492016 @default.
• W2001184349 countsByYear W20011843492018 @default.
• W2001184349 countsByYear W20011843492021 @default.
• W2001184349 crossrefType "journal-article" @default.
• W2001184349 hasAuthorship W2001184349A5001686080 @default.
• W2001184349 hasAuthorship W2001184349A5025656285 @default.
• W2001184349 hasAuthorship W2001184349A5032151940 @default.
• W2001184349 hasAuthorship W2001184349A5036535606 @default.
• W2001184349 hasAuthorship W2001184349A5038824563 @default.
• W2001184349 hasAuthorship W2001184349A5046763472 @default.
• W2001184349 hasAuthorship W2001184349A5053734699 @default.
• W2001184349 hasConcept C112887158 @default.
• W2001184349 hasConcept C121332964 @default.
• W2001184349 hasConcept C147789679 @default.
• W2001184349 hasConcept C150394285 @default.
• W2001184349 hasConcept C153642686 @default.
• W2001184349 hasConcept C161790260 @default.
• W2001184349 hasConcept C178790620 @default.
• W2001184349 hasConcept C185592680 @default.
• W2001184349 hasConcept C2776026683 @default.
• W2001184349 hasConcept C2777496208 @default.
• W2001184349 hasConcept C2777581007 @default.
• W2001184349 hasConcept C2777691172 @default.
• W2001184349 hasConcept C2780378348 @default.
• W2001184349 hasConcept C3288061 @default.
• W2001184349 hasConcept C32909587 @default.
• W2001184349 hasConcept C512735826 @default.
• W2001184349 hasConcept C521977710 @default.
• W2001184349 hasConcept C8010536 @default.
• W2001184349 hasConcept C82776694 @default.
• W2001184349 hasConcept C97355855 @default.
• W2001184349 hasConceptScore W2001184349C112887158 @default.
• W2001184349 hasConceptScore W2001184349C121332964 @default.
• W2001184349 hasConceptScore W2001184349C147789679 @default.
• W2001184349 hasConceptScore W2001184349C150394285 @default.
• W2001184349 hasConceptScore W2001184349C153642686 @default.
• W2001184349 hasConceptScore W2001184349C161790260 @default.
• W2001184349 hasConceptScore W2001184349C178790620 @default.
• W2001184349 hasConceptScore W2001184349C185592680 @default.
• W2001184349 hasConceptScore W2001184349C2776026683 @default.
• W2001184349 hasConceptScore W2001184349C2777496208 @default.
• W2001184349 hasConceptScore W2001184349C2777581007 @default.
• W2001184349 hasConceptScore W2001184349C2777691172 @default.
• W2001184349 hasConceptScore W2001184349C2780378348 @default.
• W2001184349 hasConceptScore W2001184349C3288061 @default.

• next