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- W2001206775 abstract "The structural characterization of the products obtained from the chromium(II)-pySO3 system (pySO3 = anion of 3-pyridinesulphonic acid) from both aqueous and pyridine solutions is presented. The aquo compound [Cr(pySO3)2(H2O)2]n (I) crystallizes in the monoclinic space group P21/c in an extended structure with a = 7.723(1), b = 12.995(4), c = 7.276(3) Å, β = 100.24(2)°, V = 718.6(7) Å3 and Z = 2. Cr(pySO3)2(py)4 (II) possesses a molecular structure and crystallizes in the monoclinic space group C2/c with a = 17.084(4), b = 11.031(3), c = 17.828(7) Å, β = 112.02(2)°, V = 3115(3) and Z = 4. The coordination about the chromium atom is, in both cases, highly distorted. Both compounds are relatively stable towards oxygen in the solid state, especially I." @default.
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- W2001206775 date "1992-01-01" @default.
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- W2001206775 title "Synthesis and X-ray structure of two relatively air-stable chromium(II) 3-pyridinesulphonate compounds" @default.
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- W2001206775 doi "https://doi.org/10.1016/s0277-5387(00)83566-4" @default.
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