FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001241908> ?p ?o ?g. }

• W2001241908 endingPage "3832" @default.
• W2001241908 startingPage "3824" @default.
• W2001241908 abstract "Baseline separation of ten new substituted [1-(imidazo-1-yl)-1-phenylmethyl)] benzothiazolinone and benzoxazolinone derivatives, with one chiral center, was achieved by CD-EKC using highly sulfated CDs (alpha, beta, gamma highly S-CDs) as chiral selectors. The influence of the type and concentration of the chiral selectors on the enantioseparations was investigated. The highly S-CDs exhibit a very high enantioselectivity power since they allow excellent enantiomeric resolutions compared to those obtained with the neutral CDs. The enantiomers were resolved with analysis times inferior to 2.5 min and resolution factors R(s) of 3.73, 3.90, 1.40, and 4.35 for compounds 1, 2, 3, and 5, respectively, using 25 mM phosphate buffer at pH 2.5 containing either highly S-alpha-CD, highly S-beta-CD, and highly S-gamma-CD (3 or 4% w/v) at 298 K, with an applied field of 0.30 kV/cm. The determination of the enantiomer migration order for the various analytes and the study of the analyte structure-enantioseparation relationships display the high contribution of the interactions between the analytes phenyl ring and the CDs to the enantiorecognition process. The thermodynamic study of the analyte-CD affinities permits us to improve our knowledge about the enantioseparation mechanism." @default.
• W2001241908 created "2016-06-24" @default.
• W2001241908 creator A5048948927 @default.
• W2001241908 creator A5060304025 @default.
• W2001241908 creator A5064580314 @default.
• W2001241908 creator A5068389054 @default.
• W2001241908 creator A5069337254 @default.
• W2001241908 creator A5074599262 @default.
• W2001241908 date "2005-10-01" @default.
• W2001241908 modified "2023-10-16" @default.
• W2001241908 title "Enantioseparation of chiralN-imidazole derivatives by electrokinetic chromatography using highly sulfated cyclodextrins: Mechanism of enantioselective recognition" @default.
• W2001241908 cites W1500172437 @default.
• W2001241908 cites W1554220402 @default.
• W2001241908 cites W1570474245 @default.
• W2001241908 cites W1973371461 @default.
• W2001241908 cites W1982530236 @default.
• W2001241908 cites W1990147398 @default.
• W2001241908 cites W2001507182 @default.
• W2001241908 cites W2002129736 @default.
• W2001241908 cites W2012165221 @default.
• W2001241908 cites W2017227663 @default.
• W2001241908 cites W2019612727 @default.
• W2001241908 cites W2020641614 @default.
• W2001241908 cites W2043550850 @default.
• W2001241908 cites W2047933151 @default.
• W2001241908 cites W2050326901 @default.
• W2001241908 cites W2056438709 @default.
• W2001241908 cites W2058783543 @default.
• W2001241908 cites W2061174638 @default.
• W2001241908 cites W2063938671 @default.
• W2001241908 cites W2066309309 @default.
• W2001241908 cites W2071072360 @default.
• W2001241908 cites W2071222078 @default.
• W2001241908 cites W2073140440 @default.
• W2001241908 cites W2076649807 @default.
• W2001241908 cites W2114661869 @default.
• W2001241908 cites W2124666022 @default.
• W2001241908 cites W2133295687 @default.
• W2001241908 cites W2145209032 @default.
• W2001241908 cites W2157087863 @default.
• W2001241908 doi "https://doi.org/10.1002/elps.200500078" @default.
• W2001241908 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16217831" @default.
• W2001241908 hasPublicationYear "2005" @default.
• W2001241908 type Work @default.
• W2001241908 sameAs 2001241908 @default.
• W2001241908 citedByCount "15" @default.
• W2001241908 countsByYear W20012419082013 @default.
• W2001241908 countsByYear W20012419082021 @default.
• W2001241908 crossrefType "journal-article" @default.
• W2001241908 hasAuthorship W2001241908A5048948927 @default.
• W2001241908 hasAuthorship W2001241908A5060304025 @default.
• W2001241908 hasAuthorship W2001241908A5064580314 @default.
• W2001241908 hasAuthorship W2001241908A5068389054 @default.
• W2001241908 hasAuthorship W2001241908A5069337254 @default.
• W2001241908 hasAuthorship W2001241908A5074599262 @default.
• W2001241908 hasConcept C10390740 @default.
• W2001241908 hasConcept C146686406 @default.
• W2001241908 hasConcept C147789679 @default.
• W2001241908 hasConcept C155138218 @default.
• W2001241908 hasConcept C161790260 @default.
• W2001241908 hasConcept C178790620 @default.
• W2001241908 hasConcept C185592680 @default.
• W2001241908 hasConcept C21951064 @default.
• W2001241908 hasConcept C27703432 @default.
• W2001241908 hasConcept C2779433975 @default.
• W2001241908 hasConcept C2780874372 @default.
• W2001241908 hasConcept C43617362 @default.
• W2001241908 hasConcept C486523 @default.
• W2001241908 hasConcept C55493867 @default.
• W2001241908 hasConcept C71240020 @default.
• W2001241908 hasConceptScore W2001241908C10390740 @default.
• W2001241908 hasConceptScore W2001241908C146686406 @default.
• W2001241908 hasConceptScore W2001241908C147789679 @default.
• W2001241908 hasConceptScore W2001241908C155138218 @default.
• W2001241908 hasConceptScore W2001241908C161790260 @default.
• W2001241908 hasConceptScore W2001241908C178790620 @default.
• W2001241908 hasConceptScore W2001241908C185592680 @default.
• W2001241908 hasConceptScore W2001241908C21951064 @default.
• W2001241908 hasConceptScore W2001241908C27703432 @default.
• W2001241908 hasConceptScore W2001241908C2779433975 @default.
• W2001241908 hasConceptScore W2001241908C2780874372 @default.
• W2001241908 hasConceptScore W2001241908C43617362 @default.
• W2001241908 hasConceptScore W2001241908C486523 @default.
• W2001241908 hasConceptScore W2001241908C55493867 @default.
• W2001241908 hasConceptScore W2001241908C71240020 @default.
• W2001241908 hasIssue "20" @default.
• W2001241908 hasLocation W20012419081 @default.
• W2001241908 hasLocation W20012419082 @default.
• W2001241908 hasOpenAccess W2001241908 @default.
• W2001241908 hasPrimaryLocation W20012419081 @default.
• W2001241908 hasRelatedWork W187071120 @default.
• W2001241908 hasRelatedWork W1968023312 @default.
• W2001241908 hasRelatedWork W1990380248 @default.
• W2001241908 hasRelatedWork W2006109347 @default.
• W2001241908 hasRelatedWork W2089529880 @default.
• W2001241908 hasRelatedWork W2092330499 @default.
• W2001241908 hasRelatedWork W2238760618 @default.
• W2001241908 hasRelatedWork W308490326 @default.

• next