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- W2001261805 abstract "A series of phosphine–phosphite ligands, derived from inexpensive d-(+)-xylose, were tested in the Rh-catalyzed asymmetric hydroformylation of styrene. Systematic variation of the phosphite moiety revealed a remarkable effect on the selectivity of the hydroformylation catalysts. High regioselectivities for 2-phenylpropanal (up to 95%) and moderate enantioselectivity were found under mild reaction conditions (25–40°C, 25 bar of syn gas). The hydroformylation results are explained by the solution structures of the intermediate species formed under hydroformylation conditions." @default.
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- W2001261805 date "2002-01-01" @default.
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- W2001261805 title "Asymmetric hydroformylation of styrene catalyzed by furanoside phosphine–phosphite–Rh(I) complexes" @default.
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- W2001261805 doi "https://doi.org/10.1016/s0957-4166(02)00030-7" @default.
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