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- W2001262823 abstract "We report experimental results on the thermal behavior, in the temperature range 350 to 10 K, of the two correlated photoluminescence bands centered at 4.2 and 3.1 eV in a-SiO2. The spectral features and their temperature dependence are compatible with a scheme of optical transitions from two excited electronic states, a singlet and a triplet, pertaining to a single point defect and strictly connected via intersystem crossing. The analysis of the interconversion process between the singlet and triplet state, as a function of temperature, suggests the presence of local environments (conformational substates) surrounding the chromophore that are frozen at low temperature and reach thermal equilibrium above T ⋍ 120 K." @default.
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- W2001262823 date "1997-08-01" @default.
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- W2001262823 title "Low temperature photoluminescence spectroscopy relationship between 3.1 and 4.2 eV bands in vitreous silica" @default.
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- W2001262823 doi "https://doi.org/10.1016/s0022-3093(97)00122-1" @default.
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