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- W2001277935 abstract "The Fourier transform spectrum of monoisotopic H3Si79Br has been recorded in the spectral range 1147-1384 cm−1, with a resolution of 0.0027 cm−1. The spectrum has been used to analyze the rotational structure of the overtone bands (2ν6)0 (parallel band) and (2ν6)±2 (perpendicular band), to deduce improved rotational constants for the ground state, and to determine those for the excited levels. More than 3000 transitions were fitted with a standard deviation σ = 0. 153 × 10−3 cm−1. The data fit with 20 free parameters accounted for the 1(2, 2)-type resonance. The bandcenters were found at 1264.438862 (15) and 1267.370983 (13) cm−1 for the parallel and the perpendicular bands, respectively. An evaluation of the M||/M⊥ transition dipole moment ratio has been made. Comparison of line intensities in the observed spectrum and in simulated spectra yielded for this ratio |M||/M⊥| = 2.2 ± 0.2." @default.
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- W2001277935 date "1994-06-01" @default.
- W2001277935 modified "2023-09-25" @default.
- W2001277935 title "High-Resolution Fourier Transform Spectrum and Rovibrational Analysis of the 2ν6 Overtone Bands of Monoisotopic H3Si79Br" @default.
- W2001277935 doi "https://doi.org/10.1006/jmsp.1994.1156" @default.
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