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- W2001309032 abstract "This study reexamined our contention that singlet oxygen ( 1 O 2 ) plays a role in the fungal degradation of lignin (BBRC 102(1981)484). Cultures of Phanerochaete chrysosporium and a photochemical 1 O 2 -generating system (riboflavin/light/O 2 ) cleaved a lignin substructure model compound, 1,2-bis(4-methoxyphenyl)propane-1,3-diol (I), by indistinguishable mechanisms. However, the rate of cleavage of I in D 2 O was the same as in H 2 O in the photochemical 1 O 2 -generating system, indicating that 1 O 2 was not involved. Furthermore, products formed from I in a chemical system for generating 1 O 2 (H 2 O 2 + NaOCl) differed from those produced by cultures or the photochemical system. It is concluded that 1 O 2 is not responsible for cleavage of I or related compounds in the fungal cultures or in the photochemical system." @default.
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- W2001309032 date "1983-02-01" @default.
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- W2001309032 title "Further study discounts role for singlet oxygen in fungal degradation of lignin model compounds" @default.
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- W2001309032 doi "https://doi.org/10.1016/s0006-291x(83)80136-3" @default.
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