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- W2001330473 abstract "Immobilized ZrO2-nanopowder (NP) in ionic liquid and different organic solvents was used as a suitable Lewis-acid for the synthesis of polycyclic heterocycles which contains pyran-based skeletons. Reaction of O-propargylated salicylaldehyde with active methylene compounds in the presence of ZrO2-NP in ionic liquid proceeds via domino Knoevenagel hetero Diels-Alder reaction of unactivated alkynes to construct the pyran skeleton. Comparison with different ionic liquids and organic solvents showed that the best results were obtained with 1-butyl-3-methylimidazolium nitrate [bmim][NO3] because of short reaction times and high yields. Carrying out the reaction under these conditions has advantages such as: high yields, short reaction times and easy work-up." @default.
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- W2001330473 date "2012-04-01" @default.
- W2001330473 modified "2023-10-18" @default.
- W2001330473 title "Zirconium oxide (NP) - ionic liquid as an efficient media for the domino Knoevenagel hetero Diels-Alder reaction with unactivated alkynes" @default.
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- W2001330473 doi "https://doi.org/10.1016/j.crci.2011.12.002" @default.
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