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• W2001375901 abstract "Photocatalytic degradation of paraoxon-ethyl (o,o-diethyl o-(4-nitrophenyl) phosphate), a well known surrogate of chemical warfare agents, in aqueous solution was studied by using titania nanoparticulate film. Reaction followed pseudo first order behaviour. Photolytic degradation reaction of paraoxon-ethyl demonstrated relatively low rate with a value of rate constant of 2.5 × 10− 3 min− 1. Whereas, degradation reaction in the presence of titania nanoparticulate film and UV light displayed enhanced rate with a value of rate constant of 6.9 × 10− 3 min− 1 due to photocatalysis. Gas chromatography–mass spectrometry analysis showed the formation of p-nitrophenol, o,o-diethyl phosphonic acid, o-ethyl, diphosphonic acid, phosphoric acid, dimerized product of o,o-diethyl phosphonic acid, acetaldehyde, and carbon dioxide due to photocatalytic degradation of paraoxon-ethyl. It indicates that, photocatalytic degradation reaction begins with destruction of P–O–C bonds. Subsequently, P, C atoms were found to be oxidized gradually, and contributed to its photocatalytic degradation." @default.
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• W2001375901 date "2012-06-01" @default.
• W2001375901 modified "2023-09-23" @default.
• W2001375901 title "Photocatalytic degradation of paraoxon-ethyl in aqueous solution using titania nanoparticulate film" @default.
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• W2001375901 doi "https://doi.org/10.1016/j.tsf.2012.04.033" @default.
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