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- W2001405057 abstract "The ground-state microwave spectrum of one rotamer of allylamine has been measured and assigned. Both conventional Stark-effect and double-resonance spectroscopy have been employed for this purpose. The spectrum was conclusively identified as due to the N-cis, N-lone-pair-trans form of the molecule by means of the rotational constants, N-quadrupole coupling constants, and dipole-moment components. We have obtained (in MHz): A0 = 16 107.2, B0 = 5 680.83, C0 = 4 409.13; χaa = −4.04 ± 0.06, χbb − χcc = 0.38 ± 0.2, and (in Debye) |μa| = 0.893 ± 0.004, |μb| = 0.06 ± 0.02. Indication for an opening of the heavy-atom skeleton bond angles compared with standard values appears to exist as in the structurally very similar molecule cis-butene-1." @default.
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- W2001405057 date "1971-06-01" @default.
- W2001405057 modified "2023-10-18" @default.
- W2001405057 title "Microwave spectrum of one rotamer of allylamine" @default.
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- W2001405057 doi "https://doi.org/10.1016/0022-2852(71)90080-4" @default.
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