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• W2001438766 abstract "Abstract Reactions of [ exo-nido -5,6,10-{Cl(Ph 3 P) 2 Ru}-5,6,10-(μ-H) 3 -10-H-7,8-R 2 -7,8-C 2 B 9 H 6 ] ( 1 , R = H; 2 , R = Me) with the chiral (2S,4S)-2,4-bis(diphenylphosphino)pentane ( 3 , S , S -bdpp) ligand proceed in benzene with replacement of both PPh 3 ligands on the metal center with the diphosphine affording the chelate exo-nido complexes [ exo-nido -5,6,10-{Cl( S , S -bdpp)Ru}-5,6,10-(μ-H) 3 -10-H-7,8-R 2 -7,8-C 2 B 9 H 6 ] ( 7 , R = H) and ( 8 , R = Me), respectively. A relatively fast and irreversible rearrangement of 7 into its closo isomer [ closo -3,3-( S , S -bdpp)-3-Cl-3-H-3,1,2-RuC 2 B 9 H 11 ] ( 4 ) occurs in solution already at room temperature. On the contrary, exo-nido -to- closo conversion of 8 proceeds in benzene (or much faster in toluene) only on heating and yields 17-electron paramagnetic complex [ closo -3,3-( S , S -bdpp)-3-Cl-1,2-Me 2 -3,1,2-RuC 2 B 9 H 9 ] ( 9 ). All exo-nido - and closo -ruthenacarboranes obtained were characterized by a combination of analytical, multinuclear NMR or EPR spectroscopic data and, in addition, by X-ray diffraction studies of both dimethylated complexes 8 and 9 ." @default.
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• W2001438766 date "2006-09-01" @default.
• W2001438766 modified "2023-09-23" @default.
• W2001438766 title "Isolation and characterization of the chelate exo-nido-ruthenacarborane intermediates formed in the thermal exo-nido-to-closo conversion of [exo-nido-5,6,10-{Cl(Ph3P)2Ru}-5,6,10-(μ-H)3-10-H-7,8-R2-7,8-C2B9H6] (R=H or Me) upon the triphenylphosphine ligand displacement with the chiral (2S,4S)-(−)-2,4-bis(diphenylphosphino)pentane" @default.
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• W2001438766 doi "https://doi.org/10.1016/j.jorganchem.2006.05.051" @default.
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