FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001479916> ?p ?o ?g. }

• W2001479916 endingPage "74" @default.
• W2001479916 startingPage "64" @default.
• W2001479916 abstract "A series of SAPO-34 catalysts with various Cu loadings (ranging 0.7–3.0 wt%) were prepared by the solid state ion exchange method (SSIE) and the acid properties of the catalysts were characterized by NH3-TPD and in situ DRIFTS. During synthesis, more Cu migrates and exchanges at the Brønsted acid sites with increasing amounts of Cu precursor during the SSIE, resulting in a monotonic reduction in the total number of Brønsted acid sites. Interestingly, the Lewis acid sites created by Cu ions linearly increased with increasing Cu loading up to 2.0 wt% and then only slightly increased with a further increase of Cu loading up to 3.0 wt%. XRD, H2-TPR, UV–vis and DRIFTS were used to probe Cu structures. From the DRIFTS, two different perturbed TOT vibrations were observed for both the zeolite skeleton and NH3 adsorption spectra, indicating two different types of exchanged Cu species exist. This is also consistent with the results of NO adsorption DRIFTS spectra, in which two different Cu2+ sites were observed to adsorb NO molecules. One of the sites was considered to be the isolated Cu2+ species and the other could be another type of exchanged Cu site, possibly CuxOy clusters (dimeric or oligomeric Cu species). The isolated Cu2+ on each sample was further identified by UV–vis and quantified by H2-TPR experiments. Based on these results, isolated Cu2+ species were found to be the active sites of NH3-SCR at low temperature. Furthermore, CuO phases were detected on the samples with high Cu loadings via XRD. The presence of CuxOy may promote NH3 oxidation by O2, leading to the observed decrease in standard SCR performance at high temperature." @default.
• W2001479916 created "2016-06-24" @default.
• W2001479916 creator A5032057273 @default.
• W2001479916 creator A5052304130 @default.
• W2001479916 creator A5066716873 @default.
• W2001479916 creator A5072344503 @default.
• W2001479916 creator A5084620906 @default.
• W2001479916 date "2014-08-01" @default.
• W2001479916 modified "2023-09-27" @default.
• W2001479916 title "NH3-SCR over Cu/SAPO-34 – Zeolite acidity and Cu structure changes as a function of Cu loading" @default.
• W2001479916 cites W1968703286 @default.
• W2001479916 cites W1970568856 @default.
• W2001479916 cites W1973712941 @default.
• W2001479916 cites W1975503728 @default.
• W2001479916 cites W1979141749 @default.
• W2001479916 cites W1982873654 @default.
• W2001479916 cites W1987516776 @default.
• W2001479916 cites W1992633888 @default.
• W2001479916 cites W1995653691 @default.
• W2001479916 cites W1997529322 @default.
• W2001479916 cites W2000521932 @default.
• W2001479916 cites W2001969779 @default.
• W2001479916 cites W2003236497 @default.
• W2001479916 cites W2003407646 @default.
• W2001479916 cites W2008040521 @default.
• W2001479916 cites W2010869192 @default.
• W2001479916 cites W2011329618 @default.
• W2001479916 cites W2014603144 @default.
• W2001479916 cites W2016210667 @default.
• W2001479916 cites W2019002372 @default.
• W2001479916 cites W2022072377 @default.
• W2001479916 cites W2027451924 @default.
• W2001479916 cites W2028204187 @default.
• W2001479916 cites W2032120167 @default.
• W2001479916 cites W2042183206 @default.
• W2001479916 cites W2042704476 @default.
• W2001479916 cites W2047540904 @default.
• W2001479916 cites W2050929451 @default.
• W2001479916 cites W2056626830 @default.
• W2001479916 cites W2063630714 @default.
• W2001479916 cites W2067976325 @default.
• W2001479916 cites W2068370865 @default.
• W2001479916 cites W2068486440 @default.
• W2001479916 cites W2070486060 @default.
• W2001479916 cites W2078869999 @default.
• W2001479916 cites W2078932921 @default.
• W2001479916 cites W2084076310 @default.
• W2001479916 cites W2084453528 @default.
• W2001479916 cites W2086081388 @default.
• W2001479916 cites W2093061442 @default.
• W2001479916 cites W2094464958 @default.
• W2001479916 cites W2135157414 @default.
• W2001479916 cites W2164337680 @default.
• W2001479916 cites W2316433103 @default.
• W2001479916 cites W2321568999 @default.
• W2001479916 cites W2325282600 @default.
• W2001479916 cites W2951987597 @default.
• W2001479916 cites W299670270 @default.
• W2001479916 doi "https://doi.org/10.1016/j.cattod.2013.11.040" @default.
• W2001479916 hasPublicationYear "2014" @default.
• W2001479916 type Work @default.
• W2001479916 sameAs 2001479916 @default.
• W2001479916 citedByCount "170" @default.
• W2001479916 countsByYear W20014799162014 @default.
• W2001479916 countsByYear W20014799162015 @default.
• W2001479916 countsByYear W20014799162016 @default.
• W2001479916 countsByYear W20014799162017 @default.
• W2001479916 countsByYear W20014799162018 @default.
• W2001479916 countsByYear W20014799162019 @default.
• W2001479916 countsByYear W20014799162020 @default.
• W2001479916 countsByYear W20014799162021 @default.
• W2001479916 countsByYear W20014799162022 @default.
• W2001479916 countsByYear W20014799162023 @default.
• W2001479916 crossrefType "journal-article" @default.
• W2001479916 hasAuthorship W2001479916A5032057273 @default.
• W2001479916 hasAuthorship W2001479916A5052304130 @default.
• W2001479916 hasAuthorship W2001479916A5066716873 @default.
• W2001479916 hasAuthorship W2001479916A5072344503 @default.
• W2001479916 hasAuthorship W2001479916A5084620906 @default.
• W2001479916 hasConcept C117760992 @default.
• W2001479916 hasConcept C145148216 @default.
• W2001479916 hasConcept C147789679 @default.
• W2001479916 hasConcept C150394285 @default.
• W2001479916 hasConcept C15752686 @default.
• W2001479916 hasConcept C161790260 @default.
• W2001479916 hasConcept C178790620 @default.
• W2001479916 hasConcept C179104552 @default.
• W2001479916 hasConcept C185592680 @default.
• W2001479916 hasConcept C2778077586 @default.
• W2001479916 hasConcept C32909587 @default.
• W2001479916 hasConcept C544153396 @default.
• W2001479916 hasConcept C544778455 @default.
• W2001479916 hasConcept C79878483 @default.
• W2001479916 hasConceptScore W2001479916C117760992 @default.
• W2001479916 hasConceptScore W2001479916C145148216 @default.
• W2001479916 hasConceptScore W2001479916C147789679 @default.
• W2001479916 hasConceptScore W2001479916C150394285 @default.
• W2001479916 hasConceptScore W2001479916C15752686 @default.

• next