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- W2001490393 abstract "Abstract The molecular motions, diffusion coefficients and activation energies of deuterated benzene in NaEMT (Ea=18.0 kJ/mol) and KL (Ea=7.3 kJ/mol) zeolites have been examined by 2 H NMR spin-lattice relaxation experiments. It was observed that two types of movement of C 6 D 6 exist. Below 183 K for KL and 263 K for NaEMT, benzene molecules adsorbed on cations and rapidly rotate around their sixfold molecular symmetry axis. Above these temperatures, benzene molecules are in isotropic motion and jump from one adsorption site to another. The mobility of benzene molecules in NaEMT and KL zeolites was compared with that in faujasite zeolites." @default.
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- W2001490393 date "2004-01-01" @default.
- W2001490393 modified "2023-09-24" @default.
- W2001490393 title "Mobility of benzene molecules in NaEMT and KL zeolitic nanostructures studied by 2H NMR technique" @default.
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- W2001490393 doi "https://doi.org/10.1016/s0167-2991(04)80704-3" @default.
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