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- W2001551837 abstract "The molecular 1 : 1 complexation of cinchona alkaloids by mono(6-deoxy-6-{[(R)-1-(hydroxymethyl)propyl]amino})-β-cyclodextrin (1) in aqueous solution has been investigated by 2D-NMR, fluorescence titration, and fluorescence-lifetime experiments. Generally, with 1 as the host, in contrast to β-cyclodextrin proper, strong binding of quinine (2; Ka=84200 M−1) and quinidine (3; Ka=27300 M−1) at pH 6.8 was observed, as monitored by an increase in fluorescence intensity, with a fair degree of diastereoisomer discrimination (ca. 3 : 1). To rationalize these results, two possible cooperative complexation modes, including specific H-bonding interactions to the chiral tether of the cyclodextrin portion, are proposed." @default.
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- W2001551837 date "2004-03-01" @default.
- W2001551837 modified "2023-09-26" @default.
- W2001551837 title "Diastereoisomer-Selective Inclusion Complexation of Cinchona Alkaloids with a Modifiedβ-Cyclodextrin: Fluorescent Behavior Enhanced by Chiral-Tether Binding. Short Communication" @default.
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- W2001551837 doi "https://doi.org/10.1002/cbdv.200490042" @default.
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