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- W2001566116 abstract "The first enantioselective copper-catalyzed cyclopropanation of N-acyl indoles is described. Using carbohydrate-based bis(oxazoline) ligands (glucoBox), the products were obtained in up to 72% ee. Cyclopropanation of N-Boc 3-methyl indole yielded a product with an all-carbon quaternary stereocenter, which is a valuable building block for the synthesis of indole alkaloids: Deprotection and rearrangement gave a tricyclic hemiaminal ester in 96% ee, which was subsequently employed as a key intermediate for the synthesis of (−)-desoxyeseroline." @default.
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- W2001566116 date "2012-09-25" @default.
- W2001566116 modified "2023-09-30" @default.
- W2001566116 title "Enantioselective Cyclopropanation of Indoles: Construction of All-Carbon Quaternary Stereocenters" @default.
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- W2001566116 doi "https://doi.org/10.1021/ol302388t" @default.
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