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- W2001566554 abstract "Abstract Cp2ZrCl2 reacts with nitric acid in CHCl3 to yield a dinuclear, doubly OH-bridged complex which can be isolated together with tetrahydrofuran of crystallization: [π-C5H5Zr(NO3)2(μ-OH)]2 · 2THF (B). The crystal data of B are as follows: space group P21/c, a 8.825(2), b 12.137(3), c 13.018(2) A, β 97.61(2)°. The unit cell contains two dinuclear centrosymmetric metal complexes and four molecules of tetrahydrofuran of crystallization. The Zr atom has a pentagonal-bipyramidal coordination geometry with the Cp group occupying an axial position, two chelating NO3 ligands and one OH bridging group in the equatorial plane, and one OH group in the other axial position." @default.
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- W2001566554 date "1984-10-01" @default.
- W2001566554 modified "2023-09-26" @default.
- W2001566554 title "Bis-μ-hydroxo-bis(π-cyclopentadienyldinitratozirkonium-(IV))tetrahydrofuran(), ein zweikerniger organozirkonium(IV)-komplex mit siebenfach koordinierten metallzentren" @default.
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- W2001566554 doi "https://doi.org/10.1016/0022-328x(84)80579-3" @default.
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