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- W2001567011 abstract "The crystal and molecular structure of isosilerolide has been determined by direct methods from intensity data collected on a diffractometer and has been refined by full-matrix least-squares to R= 0.051 over 1 407 reflections. Crystals are orthorhombic, space group P212121, with a= 9.665(1), b= 12.182(1), c= 17.835(2)Å, Z= 4. The ring junctions of the eudesmanolide nucleus are trans at C(5)–C(10) and cis at C(6)–C(7), respectively. The cyclohexene adopts a 10α-sofa conformation; the cyclohexane conformation is intermediate between a 5β, 8β-boat and 5β, 10α-twist. The γ-lactone is present in a flattened half-chair conformation. The compound investigated is the first representative of a new, so far undescribed, stereostructural group of native 5βH, 6αH, 7αH, 10αCH3-eudesman-6,12-olides." @default.
- W2001567011 created "2016-06-24" @default.
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- W2001567011 date "1983-01-01" @default.
- W2001567011 modified "2023-10-14" @default.
- W2001567011 title "Stereochemistry of a novel sesquiterpene lactone of eudesmane type. X-Ray determination of the structure of isosilerolide" @default.
- W2001567011 doi "https://doi.org/10.1039/p29830001675" @default.
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