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• W2001567802 abstract "Vibrationally resolved electronic spectra of small heteroclusters BnSm of benzene (B) and sulfur hexafluoride (S) have been obtained by resonant two-photon ionization spectroscopy. Some spectroscopic details of the B1S1 and B1S2 complexes were studied in the spectral regions near the S0S1, 000 and 610 transitions of the benzene monomer. A nonvanishing 000 vibrational band has been observed for B1S1 with a C3v equilibrium symmetry. For this cluster we have determined the ionization potential IP=9.180 +-0.005 eV as well as the binding energies of B1S1 and B1S+1. In view of the geometry of the complexes B1Sm (m=1−4) we found that until m=3 the SF6 molecules are localized on one side of the benzene molecular plane, while for B1S4 the symmetrical arrangement with two S2 groups on each side is favoured. The fragmentation of (BnSm)+ clusters is restricted to the loss of S1 molecules while emission of B1 molecules has not been observed." @default.
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• W2001567802 date "1993-03-01" @default.
• W2001567802 modified "2023-10-17" @default.
• W2001567802 title "Resonant two-photon ionization spectroscopy of small benzene—(SF6)m clusters" @default.
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• W2001567802 doi "https://doi.org/10.1016/0009-2614(93)90011-o" @default.
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