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- W2001569211 abstract "A series of polymer-supported chiral β-hydroxy amides and C2-symmetric β-hydroxy amides have been synthesized and successfully used for the enantioselective addition of phenylacetylene to aldehydes. High yields (up to 93%) and enantioselectivities (up to 92% ee) were achieved by using polymer-supported chiral β-hydroxy amide 4b. The resin 4b is reused four times, giving the product with enantioselectivity 80% ee. Fortunately, it is found that this heterogonous system is suitable not only for aromatic aldehydes but also aliphatic aldehyde. Chirality, 2010. © 2009 Wiley-Liss, Inc." @default.
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- W2001569211 date "2009-01-01" @default.
- W2001569211 modified "2023-09-23" @default.
- W2001569211 title "Enantioselective addition of phenylacetylene to aldehydes catalyzed by polymer-supported titanium(IV) complexes of β-hydroxy amides" @default.
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- W2001569211 doi "https://doi.org/10.1002/chir.20749" @default.
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