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• W2001569782 abstract "Polysulfides typically react readily with thiols, thus, reactions of endogenous cellular thiols with the polysulfide linkage in naturally-occuring pentathiepin cytotoxins are likely to be an important aspect of their biological chemistry. Here, it is reported that the reaction of thiols with the pentathiepin ring system initially produces a complex mixture of polysulfides that further decomposes in the presence of excess thiol to yield the corresponding 1,2-benzenedithiol with concomitant production of H(2)S and dimerized thiol. In this reaction, a single molecule of the pentathiepin consumes approximately six equivalents of thiol. The reaction of thiols with the pentathiepin ring system is faster than the analogous reaction involving typical di- and trisulfides." @default.
• W2001569782 created "2016-06-24" @default.
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• W2001569782 date "2003-04-01" @default.
• W2001569782 modified "2023-09-26" @default.
• W2001569782 title "Reaction of Thiols with 7-Methylbenzopentathiepin" @default.
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• W2001569782 doi "https://doi.org/10.1016/s0960-894x(03)00103-3" @default.
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