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- W2001593582 abstract "Effect of pressure on the rate of relatively slow thermal Z to E isomerizations was studied in viscous organic liquids. The results clearly demonstrated that the reactions were transferred from the activation limited to the solvent-fluctuation limited regime by an increase in the solvent viscosity. The viscosity dependence of the observed rate could be analyzed by assuming a two-step mechanism based on the two-dimensional reaction coordinate model proposed by one of the present authors. A recent Biswas-Bagchi prediction of an inverse logarithmic dependence of rate was not born out by our experimental results. A single case of a multi exponential decay is also reported." @default.
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- W2001593582 date "1998-01-01" @default.
- W2001593582 modified "2023-09-27" @default.
- W2001593582 title "Kinetics in Highly Viscous Liquid Phase Realized under High Pressure." @default.
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- W2001593582 doi "https://doi.org/10.4131/jshpreview.7.1222" @default.
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