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- W2001594480 abstract "Abstract A series of one‐dimensional (1D) double‐zigzag ({[Zn(papx) 2 (H 2 O) 2 ](ClO 4 ) 2 } n (x=so 1 , sc 3 , oc 5 , and soc 7 ) and 2D polyrotaxane ([Zn(papx) 2 (ClO 4 ) 2 ] n (x=so 2 , sc 4 , oc 6 , and soc 8 ) frameworks are synthesized by the reactions of Zn(ClO 4 ) 2 with equimolar amounts of papx (i.e., papso=1/2paps+1/2papo, papsc=1/2paps+1/2papc, papoc=1/2papo+1/2papc, and papsoc=1/3paps+1/3papo+1/3papc; paps= N , N ′‐bis(pyridylcarbonyl)‐4,4′‐diaminodiphenyl thioether, papo= N , N ′‐bis(pyridylcarbonyl)‐4,4′‐diaminodiphenyl ether, papc= N , N ′‐(methylenedi‐ p ‐phenylene)bispyridine‐4‐carboxamide). The new frameworks are isolated and characterized by single‐crystal and powder X‐ray diffraction studies, elemental analysis, and 1 H NMR spectroscopy. In addition, synthesis and structural characterization of 2D polyrotaxane frameworks of [Cu(papx) 2 (ClO 4 ) 2 ] n (x=s 9 , o 10 , and c 11 ) by the reaction of Cu(ClO 4 ) 2 with the respective dipyridylamide ligands are carried out. Based on the PXRD experiments, upon heating, the double‐zigzag frameworks of 1 , 3 , 5 , and 7 undergo structural transformation to give the respective polyrotaxane frameworks of 2 , 4 , 6 , and 8 . Moreover, grinding the solid samples of 2 , 4 , 6 , and 8 in the presence of moisture also result in the total conversion back into the double‐zigzag frameworks of 1 , 3 , 5 , and 7 , respectively. Remarkably, grinding the solid samples of polyrotaxane frameworks of 9 and 10 in the presence of moisture fails to induce a structural transformation process." @default.
- W2001594480 created "2016-06-24" @default.
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- W2001594480 date "2015-02-26" @default.
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- W2001594480 title "Structural Transformation of Zn<sup>II</sup>-Dipyridylamide-Based Coordination Frameworks: Hybrid-Ligand and Metal Effects" @default.
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- W2001594480 doi "https://doi.org/10.1002/cplu.201402453" @default.
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