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- W2001594906 abstract "In order to clarify the relationship between the isomerization and polymerization of α- and β-olefins by various types of catalysts, the isomerizations of allylbenzene and propenylbenzene during their polymerizations were studied. In the presence of cationic catalysts (AlBr3, BF3O(C2H5)2, etc), neither the polymerization nor the isomerization of allylbenzene was observed, but propenylbenzene was found to be polymerized without the isomerization of the monomer to give a solid polymer which consisted substantially of a 1,2-structure, plus a minor unit of an isomerized structure. In the cases of the Natta catalysts [TiCl3-Al(C2H5)3, Al/Ti≥2], allylbenzene could easily be polymerized to a high-molecular-weight polymer with a 1,2-structure. During this polymerization, both positional and geometrical isomerizations of the unreacted monomer were observed, indicating that the propenylbenzene obtained from the isomerization did not participate in the polymerization of allylbenzene. It was also found that the polymerization and the positional isomerization of propenylbenzene by these catalysts did not occur." @default.
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- W2001594906 date "1968-04-01" @default.
- W2001594906 modified "2023-10-17" @default.
- W2001594906 title "Polymerization and Isomerization of Allylbenzene and Propenylbenzene" @default.
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- W2001594906 doi "https://doi.org/10.1246/bcsj.41.953" @default.
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