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- W2001631176 abstract "The successful application of molybdate flux for the crystal growth of complex tantalum oxide, verbi causa kalitantite, was shown at a submillimetre scale. The structure was determined via X-ray single crystal refinements (space group Rc, a = 627.32(2) pm, c = 3685.75(13) pm, V = 1256.11(7) pm3 × 10−6, Z = 6) to be an α-U3O8-type layered compound presenting the general formula Mx(Nb,Ta)3n+1O8n+3 (where n = 1 in the case of M being Na, Ca or Ag and n = 2 when M is La–Eu, Y or Bi), thus corroborating earlier studies. Experimental evaluations and complementary ab initio calculations revealed the semiconductor nature of K2Ta4O11. The former were used to explain the vibrational spectrum in the mid-infrared range of wavenumbers." @default.
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- W2001631176 date "2013-01-01" @default.
- W2001631176 modified "2023-10-16" @default.
- W2001631176 title "K2Ta4O11 (“kalitantite”): a wide band gap semiconductor synthesized in molybdate flux medium" @default.
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- W2001631176 doi "https://doi.org/10.1039/c3ce27067j" @default.
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