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- W2001655263 abstract "The radical cations of dibenzofuran 1, a variety of symmetrically methylated dibenzofurans, viz. 1,9- 2,2,8- 3,3,7- 4 and 4,6-dimethyldibenzofuran 5,2,4,6,8- 6 and 1,3,7,9-tetramethyldibenzofuran 7,1,3,4,6,7,9-hexamethyl- 8 and octamethyl-dibenzofuran 9, the three symmetrical dehydrodimers, 2,2′-10,3,3′-11 and 4,4′-bidibenzofuran 12 and the unsymmetrical dehydrodimer 2,3′-bidibenzofuran 13 have been studied by cyclic voltammetry and EPR spectroscopy. For the latter purpose, the radical cations were generated by oxidation with thallium(III) trifluoroacetate in 1,1,1,3,3,3-hexafluoropropan-2-ol (HFP) at 22 °C or by DDQ-light oxidation in trifluoroacetic acid at –12 °C. For the dibenzofuran radical cation and its 2-deuteriated isotopomer, a matrix study was performed in CFCl3 at –196 °C." @default.
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- W2001655263 date "1996-01-01" @default.
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- W2001655263 title "EPR spectra and redox properties of radical cations of dibenzofuran, methylated dibenzofurans and bidibenzofurans: relation to the chemistry of dibenzofuran radical cation" @default.
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- W2001655263 doi "https://doi.org/10.1039/p29960001289" @default.
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