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- W2001674145 abstract "Abstract The system MnGa2S4-MnSc2S4 was studied by X-ray diffraction methods on quenched samples. Two intermediate phases are described: (1) a compound MnGa2−2xSc2xS4 for 0.2 ⩽ x ⩽ 0.3 crystallizing in the FeGa2S4-type structure and (2) a new olivine-type compound MnGaScS4 (x = 0.5), which exhibits no phase width. The structure of MnGaScS4 was determined from single-crystal X-ray diffraction data and refined to R = 0.018 (space group Pnma, No. 62, a = 1279.6(1), b = 742.6(1), c = 608.6(1) pm, Z = 4). The IR spectra of the new phases and the two border compounds are given." @default.
- W2001674145 created "2016-06-24" @default.
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- W2001674145 date "1990-10-01" @default.
- W2001674145 modified "2023-09-24" @default.
- W2001674145 title "MnGaScS4 and MnGa1.5Sc0.5S4, Two new compounds in the system MnGa2S4-MnSc2S4" @default.
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- W2001674145 doi "https://doi.org/10.1016/0022-5088(90)90591-7" @default.
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