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• W2001683542 abstract "Zirconium tetrachloride efficiently catalyzes the cyclocondensation reaction of o-phenylenediamine and a ketone in refluxing 1,2-dichloroethane to afford the corresponding 2,3-dihydro-1H-1,5-benzodiazepine in high yield. The formation of specific regioisomers and their structural elucidation are reported for the first time.Key words: zirconium tetrachloride, o-phenylenediamines, ketones, 1,5-benzodiazepines, 1 H NMR, regioisomers." @default.
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• W2001683542 date "2007-03-01" @default.
• W2001683542 modified "2023-10-16" @default.
• W2001683542 title "Zirconium(IV) chloride-catalyzed synthesis of 1,5-benzodiazepine derivatives" @default.
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• W2001683542 doi "https://doi.org/10.1139/v07-019" @default.
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