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- W2001714775 abstract "The Mössbauer spectra, and magnetic and electrical properties of Ba1+xFe2S4 infinitely adaptive phases with 0.074 ≤ x ≤ 0.142 and of BaFe2S4 were studied. The properties are highly anisotropic because of the presence in the structure of one-dimensional infinite chains of edge sharing FeS4 tetrahedra. BaFe2S4 is a semiconductor, Eg = 0.66 eV; magnetic susceptibility can be fit by a one-dimensional Heisenberg model with spin 52 and Jk = −30°K. The Ba1+xFe2S4 phases have Curie-Weiss behavior with an effective moment of about 2 B.M. The moment increases with x. These phases are metallic. The Mössbauer isomer shift varies linearly with valence, increasing with increasing x. The single quadrupole split absorption line characteristic of these compounds disappears at about 270°K and a complex spectrum consisting of overlapping hyperfine patterns appears at lower temperatures. Magnetic short-range ordering is responsible for this behavior although the susceptibility in this temperature range does not reflect this effect." @default.
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- W2001714775 date "1982-02-01" @default.
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- W2001714775 title "Mössbauer spectra, magnetic and electrical behavior of Ba1+xFe2S4 phases" @default.
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- W2001714775 doi "https://doi.org/10.1016/0022-4596(82)90192-x" @default.
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