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- W2001719208 abstract "Reaction of Ta(NMe2)5 with 10 equivalents of 2,6-Me2C6H3SH in toluene resulted in the formation of bright red crystals of [Ta(SC6H3Me2-2,6)4(NMe2)] (1). The related reaction between Ti(NEt2)4 and 10 equivalents of ButSH in toluene afforded a mixture of two complexes, [Ti(SBut)4] (3) and [Ti(SBut)3(NEt2)] (4). X-Ray crystal structures of 1 and 4 have been determined. Vapour phase thin-film studies of compounds 1 and 3/4 revealed that 1 is not an effective tantalum sulfide precursor whereas 3/4 produced TiS2." @default.
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- W2001719208 date "2001-01-01" @default.
- W2001719208 modified "2023-09-23" @default.
- W2001719208 title "Thiolate derivatives of titanium(iv) and tantalum(v) as precursors to metal sulfides" @default.
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- W2001719208 doi "https://doi.org/10.1039/b104888k" @default.
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