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• W2001723453 abstract "Relativistic self-consistent charge Dirac–Slater discrete variational method calculations have been done for the series of molecules MBr5, where M=Nb, Ta, Pa, and element 105, Ha. The electronic structure data show that the trends within the group 5 pentabromides resemble those for the corresponding pentaclorides with the latter being more ionic. Estimation of the volatility of group 5 bromides has been done on the basis of the molecular orbital calculations. According to the results of the theoretical interpretation HaBr5 seems to be more volatile than NbBr5 and TaBr5." @default.
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• W2001723453 date "1992-07-15" @default.
• W2001723453 modified "2023-09-23" @default.
• W2001723453 title "Relativistic effects in physics and chemistry of element 105. II. Electronic structure and properties of group 5 elements bromides" @default.
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• W2001723453 doi "https://doi.org/10.1063/1.463291" @default.
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