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- W2001724101 abstract "With increasing temperature the infrared absorption bands of Mg(OH)2 shift to lower wave numbers and the strong absorption maximum between 660–300 cm−1 shows a marked decrease in intensity. The unexpectedly large positive temperature shift of the OH-stretching band at 3700 cm−1 is related to the thermal expansion of the Mg(OH)2 lattice, which is anisotropic having its largest value parallel to the mean OH-vector. The shift can be explained by an electrostatic model taking into account the next-to-nearest neighbours of the OH−-group. The true O—H bond distance probably increases beyond the value of 0·984 Å extrapolated for Ca(OH)2 at low temperatures." @default.
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- W2001724101 date "1970-01-01" @default.
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- W2001724101 title "Infrarotspektren von Mg(OH)2 bei erhöhten temperaturen" @default.
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- W2001724101 doi "https://doi.org/10.1016/0584-8539(70)80260-4" @default.
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