FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001738122> ?p ?o ?g. }

• W2001738122 endingPage "81" @default.
• W2001738122 startingPage "72" @default.
• W2001738122 abstract "Surface oxides on Pd electrodes were formed by anodic polarization in 0.5 M aqueous H2SO4 at various potentials, Ep, from 0.80 to 1.80 V, for polarization times, tp, up to 104 s and at 278≤T≤338 K. Application of Ep between 0.80 and 1.00 V resulted in formation of a thin oxide layer that revealed one feature in the oxide–reduction profiles, the peak OC1. Upon application of Ep>1.00 V, development of a thick surface oxide commenced and the oxide–reduction profiles showed an increase of OC1 and a voltammetric wave, VW1, at a higher potential with respect to OC1. The OC1 feature corresponded to PdO reduction and VW1 to reduction of PdO2. It was observed that the growth of the thin (inner) oxide layer (OC1 peak) always preceded the development of the thick (outer) one (VW1), thus the oxide film had a two-layer structure. The oxide growth behavior was influenced by the experimental conditions such as Ep and tp, and in general the higher Ep and the longer tp, the thicker the oxide (apart from polarization at 0.80 ≤ Ep ≤ 0.95 V for tp ≥ 102 s when the initial Pd dissolution occurred). Temperature augmentation also affected the oxide thickness (for Ep and tp constant), yet did not result in new oxide species. Theoretical data treatment indicated that Pd oxide growth followed two distinct kinetic laws each one arising from a different mechanism: (i) logarithmic growth at 0.95≤Ep≤1.40 V, thus when PdO was formed; and (ii) inverse-logarithmic growth at Ep>1.40 V, thus when PdO2 was developed on top of PdO. The logarithmic growth originated from the interfacial place exchange between Ochem and the top-most Pd atoms, whereas the inverse-logarithmic law arose from the process being limited by the escape of the metal cation from the metal into the oxide at the inner metal | oxide interface. The dipole charge, δ, assigned to the surface dipole moment of the PdO layer was of the order of 0.1–0.3 of an electron. The strength of the electric field that assisted the interfacial Pd cation escape was of the order of 108–109 V m−1." @default.
• W2001738122 created "2016-06-24" @default.
• W2001738122 creator A5022922272 @default.
• W2001738122 creator A5034496793 @default.
• W2001738122 creator A5074984669 @default.
• W2001738122 date "2001-04-01" @default.
• W2001738122 modified "2023-10-18" @default.
• W2001738122 title "Influence of temperature on the growth of surface oxides on palladium electrodes" @default.
• W2001738122 cites W1974705390 @default.
• W2001738122 cites W1976793933 @default.
• W2001738122 cites W1978916568 @default.
• W2001738122 cites W1984693235 @default.
• W2001738122 cites W1988697545 @default.
• W2001738122 cites W1991496401 @default.
• W2001738122 cites W1999409867 @default.
• W2001738122 cites W2002336779 @default.
• W2001738122 cites W2002542757 @default.
• W2001738122 cites W2012057882 @default.
• W2001738122 cites W2013765942 @default.
• W2001738122 cites W2013903153 @default.
• W2001738122 cites W2014001425 @default.
• W2001738122 cites W2018097956 @default.
• W2001738122 cites W2023679097 @default.
• W2001738122 cites W2025650710 @default.
• W2001738122 cites W2029687732 @default.
• W2001738122 cites W2031961184 @default.
• W2001738122 cites W2037020393 @default.
• W2001738122 cites W2047403616 @default.
• W2001738122 cites W2047556091 @default.
• W2001738122 cites W2050613113 @default.
• W2001738122 cites W2051093718 @default.
• W2001738122 cites W2051472889 @default.
• W2001738122 cites W2053485976 @default.
• W2001738122 cites W2054790262 @default.
• W2001738122 cites W2055424078 @default.
• W2001738122 cites W2066504567 @default.
• W2001738122 cites W2083535619 @default.
• W2001738122 cites W2084372480 @default.
• W2001738122 cites W2090443042 @default.
• W2001738122 cites W2093898433 @default.
• W2001738122 cites W4231471097 @default.
• W2001738122 cites W4240338349 @default.
• W2001738122 cites W4256691584 @default.
• W2001738122 doi "https://doi.org/10.1016/s0022-0728(00)00505-2" @default.
• W2001738122 hasPublicationYear "2001" @default.
• W2001738122 type Work @default.
• W2001738122 sameAs 2001738122 @default.
• W2001738122 citedByCount "61" @default.
• W2001738122 countsByYear W20017381222012 @default.
• W2001738122 countsByYear W20017381222013 @default.
• W2001738122 countsByYear W20017381222014 @default.
• W2001738122 countsByYear W20017381222015 @default.
• W2001738122 countsByYear W20017381222016 @default.
• W2001738122 countsByYear W20017381222017 @default.
• W2001738122 countsByYear W20017381222018 @default.
• W2001738122 countsByYear W20017381222021 @default.
• W2001738122 countsByYear W20017381222022 @default.
• W2001738122 countsByYear W20017381222023 @default.
• W2001738122 crossrefType "journal-article" @default.
• W2001738122 hasAuthorship W2001738122A5022922272 @default.
• W2001738122 hasAuthorship W2001738122A5034496793 @default.
• W2001738122 hasAuthorship W2001738122A5074984669 @default.
• W2001738122 hasConcept C113196181 @default.
• W2001738122 hasConcept C147789679 @default.
• W2001738122 hasConcept C161790260 @default.
• W2001738122 hasConcept C17525397 @default.
• W2001738122 hasConcept C178790620 @default.
• W2001738122 hasConcept C179104552 @default.
• W2001738122 hasConcept C184651966 @default.
• W2001738122 hasConcept C185592680 @default.
• W2001738122 hasConcept C205049153 @default.
• W2001738122 hasConcept C2779851234 @default.
• W2001738122 hasConcept C502130503 @default.
• W2001738122 hasConcept C52859227 @default.
• W2001738122 hasConcept C544153396 @default.
• W2001738122 hasConcept C88380143 @default.
• W2001738122 hasConceptScore W2001738122C113196181 @default.
• W2001738122 hasConceptScore W2001738122C147789679 @default.
• W2001738122 hasConceptScore W2001738122C161790260 @default.
• W2001738122 hasConceptScore W2001738122C17525397 @default.
• W2001738122 hasConceptScore W2001738122C178790620 @default.
• W2001738122 hasConceptScore W2001738122C179104552 @default.
• W2001738122 hasConceptScore W2001738122C184651966 @default.
• W2001738122 hasConceptScore W2001738122C185592680 @default.
• W2001738122 hasConceptScore W2001738122C205049153 @default.
• W2001738122 hasConceptScore W2001738122C2779851234 @default.
• W2001738122 hasConceptScore W2001738122C502130503 @default.
• W2001738122 hasConceptScore W2001738122C52859227 @default.
• W2001738122 hasConceptScore W2001738122C544153396 @default.
• W2001738122 hasConceptScore W2001738122C88380143 @default.
• W2001738122 hasIssue "1-2" @default.
• W2001738122 hasLocation W20017381221 @default.
• W2001738122 hasOpenAccess W2001738122 @default.
• W2001738122 hasPrimaryLocation W20017381221 @default.
• W2001738122 hasRelatedWork W1980023817 @default.
• W2001738122 hasRelatedWork W1992358679 @default.
• W2001738122 hasRelatedWork W2000144188 @default.
• W2001738122 hasRelatedWork W2001706465 @default.

• next