Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001747265> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2001747265 endingPage "132" @default.
- W2001747265 startingPage "121" @default.
- W2001747265 abstract "Abstract Carbonylations (hydroformylation and hydrocarbonylation) catalyzed by the Co2(CO)8-1,2-bis(diphenylphosphino)ethane (dpe) system under CO/H2O and CO/H2 are discussed. In the hydroformylation using CO/H2 as well as hydroformylation and hydrocarbonylation using CO/H2O, the most active catalyst was formed with a ca. 1:1 ratio of phosphorus to cobalt (= dpe/Co2(CO)8). Monophosphines such as PPh3are less effective ligands for these carbonylations using CO/H2O than is dpe. The order of reactivity of the catalysts for hydroformylation using CO/H2 was Co2(CO)8-dpe > Co2(CO)8 > Co2(CO)8-PPh3. Evidence suggests that the active species which catalyses the carbonylations with CO/H2O participates in the hydroformylation with CO/H2. Comprehensive schemes of these carbonylations, which were performed under two different sets of conditions, are proposed. This is the first report that the catalyst is effective for aminomethylation using CO/H2O; N-butylmorpholines were produced in 89% yield from the reaction of propylene with morpholine as the secondary amine." @default.
- W2001747265 created "2016-06-24" @default.
- W2001747265 creator A5009487674 @default.
- W2001747265 creator A5042762412 @default.
- W2001747265 creator A5079099744 @default.
- W2001747265 date "1984-02-01" @default.
- W2001747265 modified "2023-10-13" @default.
- W2001747265 title "Carbonylations with CO/H2O and CO/H2 catalyzed by Co2(CO)8-1,2-BIS(diphenylphosphino)ethane complexes" @default.
- W2001747265 cites W1967708296 @default.
- W2001747265 cites W2003219427 @default.
- W2001747265 cites W2007979745 @default.
- W2001747265 cites W2014486415 @default.
- W2001747265 cites W2018536822 @default.
- W2001747265 cites W2024867512 @default.
- W2001747265 cites W2025730604 @default.
- W2001747265 cites W2027996770 @default.
- W2001747265 cites W2032360507 @default.
- W2001747265 cites W2032748281 @default.
- W2001747265 cites W2033750732 @default.
- W2001747265 cites W2035337680 @default.
- W2001747265 cites W2035348946 @default.
- W2001747265 cites W2036268062 @default.
- W2001747265 cites W2040757056 @default.
- W2001747265 cites W2045653653 @default.
- W2001747265 cites W2049550400 @default.
- W2001747265 cites W2050384421 @default.
- W2001747265 cites W2091717053 @default.
- W2001747265 cites W2092518803 @default.
- W2001747265 cites W2319371683 @default.
- W2001747265 cites W2343191995 @default.
- W2001747265 cites W2949166901 @default.
- W2001747265 cites W3135973123 @default.
- W2001747265 cites W3137233485 @default.
- W2001747265 cites W4236703241 @default.
- W2001747265 cites W4249748984 @default.
- W2001747265 doi "https://doi.org/10.1016/0304-5102(84)85063-4" @default.
- W2001747265 hasPublicationYear "1984" @default.
- W2001747265 type Work @default.
- W2001747265 sameAs 2001747265 @default.
- W2001747265 citedByCount "43" @default.
- W2001747265 countsByYear W20017472652012 @default.
- W2001747265 countsByYear W20017472652014 @default.
- W2001747265 countsByYear W20017472652015 @default.
- W2001747265 countsByYear W20017472652016 @default.
- W2001747265 countsByYear W20017472652017 @default.
- W2001747265 countsByYear W20017472652018 @default.
- W2001747265 countsByYear W20017472652020 @default.
- W2001747265 countsByYear W20017472652022 @default.
- W2001747265 countsByYear W20017472652023 @default.
- W2001747265 crossrefType "journal-article" @default.
- W2001747265 hasAuthorship W2001747265A5009487674 @default.
- W2001747265 hasAuthorship W2001747265A5042762412 @default.
- W2001747265 hasAuthorship W2001747265A5079099744 @default.
- W2001747265 hasConcept C155647269 @default.
- W2001747265 hasConcept C161790260 @default.
- W2001747265 hasConcept C168382676 @default.
- W2001747265 hasConcept C178790620 @default.
- W2001747265 hasConcept C185592680 @default.
- W2001747265 hasConcept C512735826 @default.
- W2001747265 hasConcept C515602321 @default.
- W2001747265 hasConcept C530467964 @default.
- W2001747265 hasConceptScore W2001747265C155647269 @default.
- W2001747265 hasConceptScore W2001747265C161790260 @default.
- W2001747265 hasConceptScore W2001747265C168382676 @default.
- W2001747265 hasConceptScore W2001747265C178790620 @default.
- W2001747265 hasConceptScore W2001747265C185592680 @default.
- W2001747265 hasConceptScore W2001747265C512735826 @default.
- W2001747265 hasConceptScore W2001747265C515602321 @default.
- W2001747265 hasConceptScore W2001747265C530467964 @default.
- W2001747265 hasIssue "1" @default.
- W2001747265 hasLocation W20017472651 @default.
- W2001747265 hasOpenAccess W2001747265 @default.
- W2001747265 hasPrimaryLocation W20017472651 @default.
- W2001747265 hasRelatedWork W1968170698 @default.
- W2001747265 hasRelatedWork W1971569654 @default.
- W2001747265 hasRelatedWork W2000510003 @default.
- W2001747265 hasRelatedWork W2001753182 @default.
- W2001747265 hasRelatedWork W2038604461 @default.
- W2001747265 hasRelatedWork W2057294401 @default.
- W2001747265 hasRelatedWork W2568477849 @default.
- W2001747265 hasRelatedWork W2950542371 @default.
- W2001747265 hasRelatedWork W2951195840 @default.
- W2001747265 hasRelatedWork W2951870253 @default.
- W2001747265 hasVolume "23" @default.
- W2001747265 isParatext "false" @default.
- W2001747265 isRetracted "false" @default.
- W2001747265 magId "2001747265" @default.
- W2001747265 workType "article" @default.