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• W2001775456 abstract "To understand the role of the superoxide (O-2) radical in chromate-related genotoxicity, we investigated whether Cr(VI) can catalyze the Haber-Weiss cycle in vitro: O-2 + Cr(VI)----Cr(V) + O2 Cr(V) + H2O2----Cr(VI) + .OH + OH-. ESR and spin trapping techniques were utilized to monitor the O-2 (produced using xanthine/xanthine oxidase), .OH, and Cr(V) species. Superoxide dismutase as well as catalase inhibited the .OH radical radical formation, attesting to the direct involvement of O-2 and H2O2 in the process. ESR measurements also provided direct evidence for the formation of Cr(V). Kinetic measurements were consistent with the role of Cr(V) and H2O2 as intermediates in .OH formation. These results indicate that in cellular media, especially during chromate phagocytosis, the O-2 radical can become a significant source of .OH radicals and hence a significant factor in the biochemical mechanism of cellular damage due to Cr(VI) exposure." @default.
• W2001775456 created "2016-06-24" @default.
• W2001775456 creator A5003636671 @default.
• W2001775456 creator A5088517899 @default.
• W2001775456 date "1992-01-01" @default.
• W2001775456 modified "2023-09-23" @default.
• W2001775456 title "The role of superoxide radical in chromium(VI)-generated hydroxyl radical: The Cr(VI) haber-weiss cycle" @default.
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• W2001775456 doi "https://doi.org/10.1016/0003-9861(92)90085-b" @default.
• W2001775456 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/1309299" @default.
• W2001775456 hasPublicationYear "1992" @default.
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