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- W2001787892 abstract "The validation of time-temperature superposition of non-linear parameters obtained from large amplitude oscillatory shear is investigated for a model viscoelastic fluid. Oscillatory time sweeps were performed on a 11 wt.% solution of high molecular weight polyisobutylene in pristane as a function of temperature and frequency and for a broad range of strain amplitudes varying from the linear to the highly non-linear regime. Lissajous curves show that this reference material displays strong non-linear behaviour when the strain amplitude is exceeding a critical value. Elastic and viscous Chebyshev coefficients and alternative non-linear parameters were obtained based on the framework of Ewoldt et al. (J Rheol 52(6):1427–1458, 2008) as a function of temperature, frequency and strain amplitude. For each strain amplitude, temperature shift factors a T (T) were calculated for the first order elastic and viscous Chebyshev coefficients simultaneously, so that master curves at a certain reference temperature T ref were obtained. It is shown that the expected independency of these shift factors on strain amplitude holds even in the non-linear regime. The shift factors a T (T) can be used to also superpose the higher order elastic and viscous Chebyshev coefficients and the alternative moduli and viscosities onto master curves. It was shown that the Rutgers-Delaware rule also holds for a viscoelastic solution at large strain amplitudes." @default.
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- W2001787892 date "2011-06-29" @default.
- W2001787892 modified "2023-10-16" @default.
- W2001787892 title "TTS in LAOS: validation of time-temperature superposition under large amplitude oscillatory shear" @default.
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- W2001787892 doi "https://doi.org/10.1007/s00397-011-0565-y" @default.
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