Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001798593> ?p ?o ?g. }
- W2001798593 endingPage "292" @default.
- W2001798593 startingPage "281" @default.
- W2001798593 abstract "More than 99% of 2,4,4′-trichloro-2′-hydroxydiphenylether (TCPE) by the catalytic hydrogenation over palladium/carbon was firstly dechlorinated under mild conditions. Used molecular hydrogen as the reducing agent, TCPE was completely hydrodechorinated to 2-hydroxydiphenylether (PE) at 50 °C and under normal pressure. The solvents affected not only the rate of the dechlorination, but also the selectivity of the hydrogenation. In general, the rate of the dechlorination decreased in the order of alcohols>alkanes>arenes>heterocycles. Addition of the bases (such as sodium hydroxide, sodium carbonate, sodium bicarbonate, triethylamine and pyridine, etc.) to the reaction systems also changed the rate of the reaction and the selectivity of the dechlorination. Except for pyridine, the other bases obviously accelerated the rate of the dechlorination. When the mixture of ethanol–water was used as the reaction solvent instead of ethanol, the rate of the dechlorination was remarkably improved. When a stoichiometric amount of sodium hydroxide was utilized as the proton acceptor in ethanol–water solvent, the catalytic life and the stability of the palladium/carbon were dramatically enhanced and promoted. The dechlorination process worked well in either organic solvents or aqueous solution and thus had potential application in the remediation of contaminated industrial waste water as well." @default.
- W2001798593 created "2016-06-24" @default.
- W2001798593 creator A5020430587 @default.
- W2001798593 creator A5052747544 @default.
- W2001798593 creator A5057829529 @default.
- W2001798593 creator A5058960164 @default.
- W2001798593 creator A5065418722 @default.
- W2001798593 creator A5070972302 @default.
- W2001798593 creator A5082752199 @default.
- W2001798593 date "2003-10-01" @default.
- W2001798593 modified "2023-09-26" @default.
- W2001798593 title "Catalytic hydrodechlorination of 2,4,4′-trichloro-2′-hydroxydiphenylether under mild conditions" @default.
- W2001798593 cites W1161827001 @default.
- W2001798593 cites W1964761108 @default.
- W2001798593 cites W1965498612 @default.
- W2001798593 cites W1967278479 @default.
- W2001798593 cites W1974749688 @default.
- W2001798593 cites W1977568682 @default.
- W2001798593 cites W1978262707 @default.
- W2001798593 cites W1982849289 @default.
- W2001798593 cites W1984915759 @default.
- W2001798593 cites W1989050815 @default.
- W2001798593 cites W1990945171 @default.
- W2001798593 cites W1992580609 @default.
- W2001798593 cites W1998957606 @default.
- W2001798593 cites W2001328394 @default.
- W2001798593 cites W2001693502 @default.
- W2001798593 cites W2002221500 @default.
- W2001798593 cites W2024705606 @default.
- W2001798593 cites W2026567232 @default.
- W2001798593 cites W2026749990 @default.
- W2001798593 cites W2032750237 @default.
- W2001798593 cites W2038160769 @default.
- W2001798593 cites W2045335551 @default.
- W2001798593 cites W2047309648 @default.
- W2001798593 cites W2060615858 @default.
- W2001798593 cites W2063921577 @default.
- W2001798593 cites W2067806510 @default.
- W2001798593 cites W2071764814 @default.
- W2001798593 cites W2077481700 @default.
- W2001798593 cites W2087965183 @default.
- W2001798593 cites W2094328934 @default.
- W2001798593 cites W2094638003 @default.
- W2001798593 cites W2113982022 @default.
- W2001798593 cites W2114793918 @default.
- W2001798593 cites W2130004825 @default.
- W2001798593 cites W2133737127 @default.
- W2001798593 cites W2170521311 @default.
- W2001798593 cites W3021724654 @default.
- W2001798593 cites W4233415211 @default.
- W2001798593 doi "https://doi.org/10.1016/s0926-3373(03)00173-5" @default.
- W2001798593 hasPublicationYear "2003" @default.
- W2001798593 type Work @default.
- W2001798593 sameAs 2001798593 @default.
- W2001798593 citedByCount "32" @default.
- W2001798593 countsByYear W20017985932012 @default.
- W2001798593 countsByYear W20017985932013 @default.
- W2001798593 countsByYear W20017985932014 @default.
- W2001798593 countsByYear W20017985932015 @default.
- W2001798593 countsByYear W20017985932016 @default.
- W2001798593 countsByYear W20017985932018 @default.
- W2001798593 countsByYear W20017985932020 @default.
- W2001798593 countsByYear W20017985932022 @default.
- W2001798593 crossrefType "journal-article" @default.
- W2001798593 hasAuthorship W2001798593A5020430587 @default.
- W2001798593 hasAuthorship W2001798593A5052747544 @default.
- W2001798593 hasAuthorship W2001798593A5057829529 @default.
- W2001798593 hasAuthorship W2001798593A5058960164 @default.
- W2001798593 hasAuthorship W2001798593A5065418722 @default.
- W2001798593 hasAuthorship W2001798593A5070972302 @default.
- W2001798593 hasAuthorship W2001798593A5082752199 @default.
- W2001798593 hasConcept C118792377 @default.
- W2001798593 hasConcept C161790260 @default.
- W2001798593 hasConcept C175113610 @default.
- W2001798593 hasConcept C178790620 @default.
- W2001798593 hasConcept C179104552 @default.
- W2001798593 hasConcept C184651966 @default.
- W2001798593 hasConcept C185592680 @default.
- W2001798593 hasConcept C2775896084 @default.
- W2001798593 hasConcept C2778562268 @default.
- W2001798593 hasConcept C2778657360 @default.
- W2001798593 hasConcept C2779485729 @default.
- W2001798593 hasConcept C2780471494 @default.
- W2001798593 hasConcept C2781283055 @default.
- W2001798593 hasConcept C502130503 @default.
- W2001798593 hasConcept C512968161 @default.
- W2001798593 hasConcept C537181965 @default.
- W2001798593 hasConceptScore W2001798593C118792377 @default.
- W2001798593 hasConceptScore W2001798593C161790260 @default.
- W2001798593 hasConceptScore W2001798593C175113610 @default.
- W2001798593 hasConceptScore W2001798593C178790620 @default.
- W2001798593 hasConceptScore W2001798593C179104552 @default.
- W2001798593 hasConceptScore W2001798593C184651966 @default.
- W2001798593 hasConceptScore W2001798593C185592680 @default.
- W2001798593 hasConceptScore W2001798593C2775896084 @default.
- W2001798593 hasConceptScore W2001798593C2778562268 @default.
- W2001798593 hasConceptScore W2001798593C2778657360 @default.
- W2001798593 hasConceptScore W2001798593C2779485729 @default.