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- W2001799158 abstract "Abstract Lithium loss from LiCoO 2 following isochronal thermal treatment for 5 h in the temperature range 850–1300°C was determined by thermogravimetric (TGA) and diffractometric (XRD) measurements. Lithium vaporization starts from 900°C, and following thermal treatment at 1300°C 85% of lithium was lost. At 1050°C a change in the mechanism of lithium and oxygen evaporation was observed. Initially, following lithium loss, Li y Co 2− y O 2 (solid solution of CoO in LiCoO 2 ) was formed. An activation energy of 305 kJ mol −1 , not too far from the heat of reaction from Li 2 O to Li 2 O 2 vapour, was obtained. Phase transition to cubic Li 0.065 Co 0.935 O structure occurred starting from thermal treatment at 1050°C. Both hexagonal and cubic lithium cobalt oxide structures were subjected to phase transition to get LiCoO 2 and Co 3 O 4 during cooling, but the cubic phase was stabilized against phase transition with increasing temperature." @default.
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- W2001799158 date "2001-11-01" @default.
- W2001799158 modified "2023-09-26" @default.
- W2001799158 title "Lithium loss from lithium cobalt oxide: hexagonal Li0.5Co0.5O to cubic Li0.065Co0.935O phase transition" @default.
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- W2001799158 doi "https://doi.org/10.1016/s1466-6049(01)00185-4" @default.
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