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- W2001804880 abstract "Abstract Although esters of methanesulfonic acid and E-toluene-sulfonic acid have similar reactivity in substitution reac-tions, their photochemical behavior is quite different, E-Toluenesulfonates experience photochemical desulfonation in the presence of amines, a reaction which regenerates the parent alcohols (eq 1) in good to excellent yields and thus allows the E-tolylsulfonyl group to become an effective photoremovable protecting group. 1–4 In contrast, photolysis of methanesulfonates is not regarded as a viable method for group deprotection since deprotection is accompanied by reduction (eq 2).5" @default.
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- W2001804880 date "1992-02-01" @default.
- W2001804880 modified "2023-10-16" @default.
- W2001804880 title "Photochemical Reactions of Methanesulfonates. A New Deprotection Reaction" @default.
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- W2001804880 doi "https://doi.org/10.1080/07328309208017799" @default.
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