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- W2001818124 abstract "From annelation to an elation: The surprising stability of pyridoannelated imidazol-2-ylidenes (see scheme) in comparison with the heavier Group 14 homologues suggests broad tuning potential and control of the reactivity by the lone pair of electrons at the carbon atom. The asymmetric distribution of π-electron density, which destabilizes the heavier homologues, does not markedly diminish the kinetic stability of the N-heterocyclic carbenes (NHCs)." @default.
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- W2001818124 date "2007-03-23" @default.
- W2001818124 modified "2023-10-17" @default.
- W2001818124 title "Stabilization of Unsymmetrically Annelated Imidazol-2-ylidenes with Respect to Their Higher Group 14 Homologues by n-/π-HOMO Inversion" @default.
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- W2001818124 doi "https://doi.org/10.1002/anie.200604516" @default.
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