Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001864662> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2001864662 endingPage "338" @default.
- W2001864662 startingPage "329" @default.
- W2001864662 abstract "The reactions of Fe2(CO)9 with triple-decker sandwich complexes containing the 2-methyl-1,3,4,5-tetraethyl or the 4,5-diethyl-1,3-dimethyl derivatives of the 2,3-dihydro-1,3-diborole heterocycle C2B2C (4a,b) as a bridging ligand have been investigated. The paramagnetic triple-deckers, 32 valence electron (VE) [(η5-C5H5)-Ni(μ,η5-C2B2C)Co(η5-C5H5)] (8a) and 33 VE [(η5-C5H5)Ni(μ,η5-C2B2C)Ni(η5-C5H5)] (9b) react with Fe2(CO)9 to give products resulting either from replacement of a (η5-C5H5)Ni fragment by Fe(CO)3, or insertion of Fe(CO)3 into the (η5-C5H5)Ni bond. Thus, reaction of 8a with Fe2(CO)9 proceeds via Fe(CO)3 insertion into the (η5-C5H5)Ni bond to yield the trinuclear carbonyl-bridged complex [(η5-C5H5)FeCO(μ-CO)2Ni(μ,η5-C2B2C)Co(η5-C5H5)] (10a), and subsequently the tetranuclear [{(η5-C5H5)Co(μ,η5-C2B2C)Ni(μ-CO)}2] (12a), and also via replacement of (η5-C5H5)Ni to give the triple-decker [(η5-C5H5)Co(μ,η5-C2B2C)Fe(CO)3] (13a). 33 VE 9b reacts with Fe2(CO)9 to give initially [(η5-C5H5)Ni(μ,η5-C2B2C)Fe(CO)3] (14b); subsequent reactions lead to the carbonyl-bridged [(η5-C5H5)Fe(CO)(μ-CO)2Ni(μ,η5-C2B2C)Fe(CO)3] (15b), the tetra-decker [{(CO)3Fe(μ,η5-C2B2C)}2Ni] (16b), and the triple-decker [(η5-C5H5)Fe(μ,η5-C2B2C)Fe(CO)3] (17b). The unsymmetrical triple-decker complexes 14a and 14b have been made independently by stacking the Ni-sandwich complexes 20a and 20b with an Fe(CO)3 fragment. A close chemical relationship between 32 VE 8a and 20 VE nickelocene has been established, and may be rationalised by consideration of electronic structures." @default.
- W2001864662 created "2016-06-24" @default.
- W2001864662 creator A5050285872 @default.
- W2001864662 creator A5064198060 @default.
- W2001864662 creator A5080467744 @default.
- W2001864662 creator A5080623064 @default.
- W2001864662 date "1990-08-01" @default.
- W2001864662 modified "2023-10-16" @default.
- W2001864662 title "Triple-decker complexes XIV. Reactions of iron carbonyls with the triple-decker sandwich complexes (η5-C5H5)Ni(μ,η5-C2B2C)M(η5-C5H5), (M = Co, Ni). Replacement of (η5-C5H5)Ni by and insertion of the Fe(CO)3 fragment into the (η5-C5H5)Ni bond" @default.
- W2001864662 cites W1408768092 @default.
- W2001864662 cites W1965529528 @default.
- W2001864662 cites W1967149331 @default.
- W2001864662 cites W1969502549 @default.
- W2001864662 cites W1979652544 @default.
- W2001864662 cites W1988597145 @default.
- W2001864662 cites W2004504254 @default.
- W2001864662 cites W2060075968 @default.
- W2001864662 cites W2066906284 @default.
- W2001864662 cites W2070573582 @default.
- W2001864662 cites W2075338222 @default.
- W2001864662 cites W2078255827 @default.
- W2001864662 cites W2087293791 @default.
- W2001864662 cites W2159719595 @default.
- W2001864662 cites W2949964152 @default.
- W2001864662 doi "https://doi.org/10.1016/0022-328x(90)87242-6" @default.
- W2001864662 hasPublicationYear "1990" @default.
- W2001864662 type Work @default.
- W2001864662 sameAs 2001864662 @default.
- W2001864662 citedByCount "8" @default.
- W2001864662 countsByYear W20018646622014 @default.
- W2001864662 countsByYear W20018646622016 @default.
- W2001864662 crossrefType "journal-article" @default.
- W2001864662 hasAuthorship W2001864662A5050285872 @default.
- W2001864662 hasAuthorship W2001864662A5064198060 @default.
- W2001864662 hasAuthorship W2001864662A5080467744 @default.
- W2001864662 hasAuthorship W2001864662A5080623064 @default.
- W2001864662 hasConcept C116569031 @default.
- W2001864662 hasConcept C120665830 @default.
- W2001864662 hasConcept C121332964 @default.
- W2001864662 hasConcept C155647269 @default.
- W2001864662 hasConcept C165176872 @default.
- W2001864662 hasConcept C170493617 @default.
- W2001864662 hasConcept C178790620 @default.
- W2001864662 hasConcept C185592680 @default.
- W2001864662 hasConcept C188027245 @default.
- W2001864662 hasConcept C196099240 @default.
- W2001864662 hasConcept C207114421 @default.
- W2001864662 hasConcept C2780926202 @default.
- W2001864662 hasConcept C50515024 @default.
- W2001864662 hasConcept C544153396 @default.
- W2001864662 hasConcept C55493867 @default.
- W2001864662 hasConcept C68381374 @default.
- W2001864662 hasConcept C71240020 @default.
- W2001864662 hasConcept C8010536 @default.
- W2001864662 hasConceptScore W2001864662C116569031 @default.
- W2001864662 hasConceptScore W2001864662C120665830 @default.
- W2001864662 hasConceptScore W2001864662C121332964 @default.
- W2001864662 hasConceptScore W2001864662C155647269 @default.
- W2001864662 hasConceptScore W2001864662C165176872 @default.
- W2001864662 hasConceptScore W2001864662C170493617 @default.
- W2001864662 hasConceptScore W2001864662C178790620 @default.
- W2001864662 hasConceptScore W2001864662C185592680 @default.
- W2001864662 hasConceptScore W2001864662C188027245 @default.
- W2001864662 hasConceptScore W2001864662C196099240 @default.
- W2001864662 hasConceptScore W2001864662C207114421 @default.
- W2001864662 hasConceptScore W2001864662C2780926202 @default.
- W2001864662 hasConceptScore W2001864662C50515024 @default.
- W2001864662 hasConceptScore W2001864662C544153396 @default.
- W2001864662 hasConceptScore W2001864662C55493867 @default.
- W2001864662 hasConceptScore W2001864662C68381374 @default.
- W2001864662 hasConceptScore W2001864662C71240020 @default.
- W2001864662 hasConceptScore W2001864662C8010536 @default.
- W2001864662 hasIssue "1-3" @default.
- W2001864662 hasLocation W20018646621 @default.
- W2001864662 hasOpenAccess W2001864662 @default.
- W2001864662 hasPrimaryLocation W20018646621 @default.
- W2001864662 hasRelatedWork W1559073469 @default.
- W2001864662 hasRelatedWork W1967073575 @default.
- W2001864662 hasRelatedWork W2006907240 @default.
- W2001864662 hasRelatedWork W2049639882 @default.
- W2001864662 hasRelatedWork W2089328357 @default.
- W2001864662 hasRelatedWork W2293188621 @default.
- W2001864662 hasRelatedWork W2740288586 @default.
- W2001864662 hasRelatedWork W2952354187 @default.
- W2001864662 hasRelatedWork W4230779809 @default.
- W2001864662 hasRelatedWork W4232306871 @default.
- W2001864662 hasVolume "394" @default.
- W2001864662 isParatext "false" @default.
- W2001864662 isRetracted "false" @default.
- W2001864662 magId "2001864662" @default.
- W2001864662 workType "article" @default.