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- W200196694 abstract "An algorithm for the extraction of molecular weight distributions of typical high molecular weight, water-soluble polymers from dynamic light scattering has been developed. A function fit method was used to determine the best distribution parameters of a generalized exponential function. The algorithm employs a Marquardt-Levenburg constrained nonlinear least squares regression. A series approximation of the integral equation which is generated was attempted. This approach was abandoned because of difficulties with series convergence. A modified Rhomberg numerical integration was utilized with limited success. Two water-soluble polymer molecular weight distributions were obtained. The distributions of a polyethyleneoxide and a polyacrylamide were determined and compared with distributions obtained using gel permeation chromatography. The two methods were in fair agreement." @default.
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- W200196694 date "1991-07-18" @default.
- W200196694 modified "2023-10-14" @default.
- W200196694 title "Determination of Molecular-Weight Distribution of Water-Soluble Macromolecules by Dynamic Light Scattering" @default.
- W200196694 doi "https://doi.org/10.1021/bk-1991-0467.ch018" @default.
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