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• W2001972029 abstract "Abstract The review generalizes the published findings and the authors' own results on some general problems concerning the synthesis of high molecular weight polyorganophosphazenes with an open chain, in particular, problems of the initial polydichlorophosphazene and the unit heterogeneity of the macromolecules of the polyorganophosphazenes resulting, in the main, from the hydrolytic instability of the PCl bonds in the phosphazene structures. From analysis of the published experimental findings obtained by various investigatirs it is concluded that an important distinguishing feature of the polyphosphazenes is the high sensitivity of their properties to insignificant amounts of anomalous units which practically need not be considered for most other polymers, and which are commonly called traces. By virtue of this feature of the polyphosphazenes the successfuls solution of the problem of their synthesis and obtaining stable well reproducible results calls for a scientifically based approach to the control of the secondary processes of hydrolysis. Some of the possible lines of such an approach have already been identified and are considered in the present review." @default.
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• W2001972029 date "1982-01-01" @default.
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• W2001972029 title "Some problems in the synthesis of polyphosphazenes and possible solutions. Review" @default.
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• W2001972029 doi "https://doi.org/10.1016/0032-3950(83)90438-0" @default.
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