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- W2001993668 abstract "The relation between stereoregularity of active centers on a MgCl2/TiCl4 catalyst and functions of inside donor (ID) and outside donor (OD) was investigated in the case of ethyl benzoate (EB)/methyl p-toluate (MPT) as an ID/OD pair. The results indicate that stereregularity depends merely on the amount of MPT supported on the catalyst. On the other hand, regioregularity of active centers was investigated with a MgCl2/TiCl4/dioctyl phthalate(DOP)-Et3Al/diphenyldimethoxysilane(DPDMS) catalyst system. Regio-irregular inserted units were detected only in end groups of PP. It indicates that regio-irregular insertion leads to dormant centers with respect to propene insertion, though such centers are active for hydrogen transfer." @default.
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- W2001993668 date "1995-01-01" @default.
- W2001993668 modified "2023-09-24" @default.
- W2001993668 title "Stereoregularity and regioregularity of active centers in propene polymerization" @default.
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- W2001993668 doi "https://doi.org/10.1002/masy.19950890106" @default.
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