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- W2001999307 abstract "13C NMR spectra of three poly(vinyl alcohol)s differing in the stereoregularity (atactic, syndiotactic-rich and isotactic-rich) were determined in DMSO-d6 and D2O. The methylene and methine carbon absorptions including so far unassigned ones (mmmr heptad signals in mm-centered region and all heptad signals in mr-centered region) were completely assigned with hexads and heptads, respectively, and the assignments were quantitatively confirmed for atactic and syndiotactic-rich poly(vinyl alcohol)s. The isotactic-rich polymer showed a discrepancy between the observed and the calculated intensities, assuming the first-order Markov statistics, due to difficulty in determining its polymerization mechanism." @default.
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- W2001999307 date "2001-11-01" @default.
- W2001999307 modified "2023-10-02" @default.
- W2001999307 title "Assignment of finely resolved 13C NMR spectra of poly(vinyl alcohol)" @default.
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- W2001999307 doi "https://doi.org/10.1016/s0032-3861(01)00536-5" @default.
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