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- W2002000265 abstract "Abstract The Raman, infrared and 1H-NMR spectra of (CH3)3 -X-Si (CH3)3 (X=O,S,Se,Te) were measured, and the assignment was carried out by comparison with those of the structurally related compounds, (CH3)3 SiCl and (CH3)3 Si-Si (CH3)3. The vibrational spectra of (CH3)3 Si-X-Si (CH3)3 can be interpreted in terms of a non-rigid D3d symmetry with internal rotations, because those of skeletones of the molecules indicate the lack of coincidence between Raman and infrared frequencies. The 1H-NMR spectra also support a non-rigid D3d model, because only one band for CH3 group appears." @default.
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- W2002000265 date "1986-09-01" @default.
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- W2002000265 title "Raman, Infrared and 1H-NMR Spectra of Hexamethyldisilylchalcogenides" @default.
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- W2002000265 doi "https://doi.org/10.1080/00387018608069288" @default.
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