FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002015209> ?p ?o ?g. }

• W2002015209 endingPage "4717" @default.
• W2002015209 startingPage "4710" @default.
• W2002015209 abstract "A 19F NMR chemical shift study of a homologous series of perfluorocarbon (fc) [CxF2x+1CO2Na, x = 3, 4, 6−9] surfactants (S) has been carried out in D2O and in binary solvent (D2O + cyclodextrin (CD)) systems at 22 °C. Both β-CD and modified cyclodextrins were used. Complementary 1H NMR chemical shift data for the cyclodextrins in binary solvent (D2O + S) systems were also obtained. Values of the complex-induced chemical shifts (CIS) for selected host or guest nuclei are observed to increase with increasing alkyl chain (Cx) length of the surfactant when the CD/S complex has a 1:1 stoichiometry. However, for complexes having stoichiometries other than 1:1 CD/S, somewhat different trends in the CIS values were observed. Binding constants (Ki) have been obtained from the analysis of 19F and 1H CIS values of the CD/S systems using equilibrium models in which 1:1, 1:1 plus 2:1, 1:1 plus 1:2 complexes, and uncomplexed species are present. In general, Ki increases as Cx increases; however, differences in the binding affinity, stoichiometry, and inclusion geometry of the CD/S complexes were observed to depend on the type of cyclodextrin. The latter can be understood in terms of the steric effects created by the introduction of alkyl groups in the annulus region of the cyclodextrin." @default.
• W2002015209 created "2016-06-24" @default.
• W2002015209 creator A5005237155 @default.
• W2002015209 creator A5034470962 @default.
• W2002015209 date "1998-08-01" @default.
• W2002015209 modified "2023-10-07" @default.
• W2002015209 title "¹⁹F and ¹H NMR Investigation of Cyclodextrin/Fluorocarbon Alkyl Carboxylate Surfactant Inclusion Complexes" @default.
• W2002015209 cites W1966394851 @default.
• W2002015209 cites W1969263196 @default.
• W2002015209 cites W1975786757 @default.
• W2002015209 cites W1980434931 @default.
• W2002015209 cites W1990310358 @default.
• W2002015209 cites W1990969075 @default.
• W2002015209 cites W1994830906 @default.
• W2002015209 cites W1995710713 @default.
• W2002015209 cites W2002741007 @default.
• W2002015209 cites W2003401677 @default.
• W2002015209 cites W2007420885 @default.
• W2002015209 cites W2010207771 @default.
• W2002015209 cites W2012619409 @default.
• W2002015209 cites W2014378899 @default.
• W2002015209 cites W2020798399 @default.
• W2002015209 cites W2023547724 @default.
• W2002015209 cites W2027006710 @default.
• W2002015209 cites W2028911585 @default.
• W2002015209 cites W2036488131 @default.
• W2002015209 cites W2051799754 @default.
• W2002015209 cites W2052045852 @default.
• W2002015209 cites W2054546049 @default.
• W2002015209 cites W2061298129 @default.
• W2002015209 cites W2064646327 @default.
• W2002015209 cites W2069201669 @default.
• W2002015209 cites W2076525076 @default.
• W2002015209 cites W2085049542 @default.
• W2002015209 cites W2088323113 @default.
• W2002015209 cites W2088869613 @default.
• W2002015209 cites W2090850489 @default.
• W2002015209 cites W2091399445 @default.
• W2002015209 cites W2092084822 @default.
• W2002015209 cites W2092671012 @default.
• W2002015209 cites W2095334504 @default.
• W2002015209 cites W2116716969 @default.
• W2002015209 cites W2951309034 @default.
• W2002015209 cites W2091726836 @default.
• W2002015209 doi "https://doi.org/10.1021/la9802365" @default.
• W2002015209 hasPublicationYear "1998" @default.
• W2002015209 type Work @default.
• W2002015209 sameAs 2002015209 @default.
• W2002015209 citedByCount "54" @default.
• W2002015209 countsByYear W20020152092012 @default.
• W2002015209 countsByYear W20020152092013 @default.
• W2002015209 countsByYear W20020152092014 @default.
• W2002015209 countsByYear W20020152092015 @default.
• W2002015209 countsByYear W20020152092016 @default.
• W2002015209 countsByYear W20020152092017 @default.
• W2002015209 countsByYear W20020152092018 @default.
• W2002015209 countsByYear W20020152092019 @default.
• W2002015209 countsByYear W20020152092021 @default.
• W2002015209 countsByYear W20020152092022 @default.
• W2002015209 crossrefType "journal-article" @default.
• W2002015209 hasAuthorship W2002015209A5005237155 @default.
• W2002015209 hasAuthorship W2002015209A5034470962 @default.
• W2002015209 hasConcept C103319777 @default.
• W2002015209 hasConcept C144082473 @default.
• W2002015209 hasConcept C147789679 @default.
• W2002015209 hasConcept C178790620 @default.
• W2002015209 hasConcept C185592680 @default.
• W2002015209 hasConcept C201194858 @default.
• W2002015209 hasConcept C2776482079 @default.
• W2002015209 hasConcept C2778074193 @default.
• W2002015209 hasConcept C2778649806 @default.
• W2002015209 hasConcept C2779433975 @default.
• W2002015209 hasConcept C2780263894 @default.
• W2002015209 hasConcept C32909587 @default.
• W2002015209 hasConcept C55493867 @default.
• W2002015209 hasConcept C58226133 @default.
• W2002015209 hasConcept C71240020 @default.
• W2002015209 hasConcept C8010536 @default.
• W2002015209 hasConceptScore W2002015209C103319777 @default.
• W2002015209 hasConceptScore W2002015209C144082473 @default.
• W2002015209 hasConceptScore W2002015209C147789679 @default.
• W2002015209 hasConceptScore W2002015209C178790620 @default.
• W2002015209 hasConceptScore W2002015209C185592680 @default.
• W2002015209 hasConceptScore W2002015209C201194858 @default.
• W2002015209 hasConceptScore W2002015209C2776482079 @default.
• W2002015209 hasConceptScore W2002015209C2778074193 @default.
• W2002015209 hasConceptScore W2002015209C2778649806 @default.
• W2002015209 hasConceptScore W2002015209C2779433975 @default.
• W2002015209 hasConceptScore W2002015209C2780263894 @default.
• W2002015209 hasConceptScore W2002015209C32909587 @default.
• W2002015209 hasConceptScore W2002015209C55493867 @default.
• W2002015209 hasConceptScore W2002015209C58226133 @default.
• W2002015209 hasConceptScore W2002015209C71240020 @default.
• W2002015209 hasConceptScore W2002015209C8010536 @default.
• W2002015209 hasIssue "17" @default.
• W2002015209 hasLocation W20020152091 @default.
• W2002015209 hasOpenAccess W2002015209 @default.
• W2002015209 hasPrimaryLocation W20020152091 @default.

• next