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- W2002042164 abstract "Abstract The enolate derived from ester 15 reacts with diketone 10 stereoselectively (10:1), and the major isomer can be converted into lactone 21 . This rearranges in boiling 1,2-dichlorobenzene to afford the tricyclic lactone 22 , a model compound which shares with CP-225,917 ( 1 ) the bridgehead double bond, the C(5) quaternary center, a C(5) side chain of correct length, and the γ-lactone subunit." @default.
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- W2002042164 date "1999-10-01" @default.
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- W2002042164 title "Model studies related to CP-225,917: Stereocontrolled generation of the quaternary center" @default.
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- W2002042164 doi "https://doi.org/10.1016/s0040-4020(99)00712-7" @default.
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