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- W2002051219 abstract "Abstract The influence of Cerium doping on the structural and magnetic properties of BiFeO 3 thin films have been investigated. Rietveld refinement of X-ray diffraction data and successive de-convolution of Raman scattering spectra of Bi 1− x Ce x FeO 3 (BCFO) thin films with x =0–0.20 reflect the single phase rhombohedral (R3c) formation for x x ≥0.08. All low wavenumber Raman modes ( −1 ) showed a noticeable shift towards higher wavenumber with increase in doping concentration, except Raman E-1 mode (71 cm −1 ), shows a minor shift. Sudden evolution of Raman mode at 668 cm −1 , manifested as A 1 -tetragonal mode, accompanied by the shift to higher wavenumber with increase in doping concentration ( x ) affirm partial structural phase transition. Anomalous wasp waist shaped ( M–H ) hysteresis curves with improved saturation magnetization ( M s ) for BCFO thin films is attributed to antiferromagnetic interaction/hybridization between Ce 4f and Fe 3d electronic states. The contribution of both hard and soft phase to the total coercivity is calculated. Polycrystalline Bi 0.88 Ce 0.12 FeO 3 thin film found to exhibit better magnetic properties with M s =15.9 emu/g without any impure phase." @default.
- W2002051219 created "2016-06-24" @default.
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- W2002051219 date "2015-03-01" @default.
- W2002051219 modified "2023-10-13" @default.
- W2002051219 title "Magnetic hysteresis of cerium doped bismuth ferrite thin films" @default.
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- W2002051219 doi "https://doi.org/10.1016/j.jmmm.2014.11.062" @default.
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