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• W2002058446 abstract "The sensitizers [(4,4‘-(CO2H)2bpy)ReI(CO)3−CN−RuII(bpy)2(CN)](PF6) and [(4,4‘-(CO2H)2bpy)ReI(CO)3−NC−RuII(bpy)2(CN)](PF6), where bpy is 2,2‘-bipyridine, have been prepared, characterized, and anchored to porous nanocrystalline TiO2 surfaces for light-to-electrical energy conversion. The facial geometry about the ReI center orientates the RuII center proximate to the TiO2 surface. Long wavelength excitation is absorbed exclusively by the −RuII(bpy)2 group. Photoelectrochemical and time-resolved absorption measurements demonstrate rapid and efficient interfacial electron transfer even though the sensitizer is remote to the semiconductor-bound ligand." @default.
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• W2002058446 date "1997-01-01" @default.
• W2002058446 modified "2023-09-26" @default.
• W2002058446 title "Remote Interfacial Electron Transfer from Supramolecular Sensitizers" @default.
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• W2002058446 doi "https://doi.org/10.1021/ic960717g" @default.
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